摘要
简要叙述了一套17种陶瓷标准样品的研制方法和制作过程,并对烧成试样进行了EPMA和X射线荧光光谱分析研究。结果表明:烧成试样与古瓷胎具有相近的物相结构(或基体),且胎体致密度高、吸水率低,主成分分布均匀(X射线束斑直径为2mm,α=0.05),完全能够满足用作陶瓷标准样品的技术要求。预期可将这套标准样品用于古瓷胎中Na2O,MgO,Al2O3,SiO2,K2O,CaO,TiO2和Fe2O3等主成分的X射线荧光光谱定量分析,保证为古陶瓷研究和科学鉴定提供准确、可靠的分析数据。
The preparation of 17 kinds of ceramic standard samples（CSS）is introduced briefly in the present paper,and the experimental results of the sintered CSS by using EPMA and XRF are discussed in detail.The conclusions can be mainly drawn that the CSS,which have high density,low water absorption and good homogeneity of element distribution,have similar phase structure（or matrix）to the bodies of ancient ceramics,and perfectly meet the requirements of being used as ceramic standard samples.This set of CSS are expected to play an important role in x-ray fluorescence spectrometric quantitative analysis of Na2O,MgO,Al2O3,SiO2,K2O,CaO,TiO2 and Fe2O3 in the body of ancient ceramics and can provide accurate and reliable data for study and identification of ancient ceramics.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
2010年第11期3143-3148,共6页
Spectroscopy and Spectral Analysis
基金
国家自然科学基金项目(50432010
10675143)
中国科学院知识创新工程项目(KJCX3.SYW.N12)
国家海洋局第二海洋研究所基本科研业务费专项项目(JG0902)资助
关键词
X射线荧光光谱法
古陶瓷
标准样品
电子探针
均匀性
X-ray fluorescence spectrometry
Ancient ceramics
Standard sample
EPMA
Homogeneity
