摘要
By combined electrocatalysis and adsorption method the degradation of wastewater containing phenol was investigated.The influences of current intensity on the removal of chemical oxygen demand(CODCr),average current efficiency and energy consumption were studied.The results showed that high current density was favorable for removal of CODCr.Considering the average current efficiency and energy consumption,current of 0.6 A was chosen to be the suitable current intensity.Electrolyte could remarkably affect the removal of phenol.NaCl exhibited more significant promotion on CODCr removal than Na2SO4.Activated carbon fiber,based on its adsorption and electrochemical character,was used as cathode material to degrade the phenol.It was found that the removal rate of CODCr could reach 90% after 10 min treatment by the combination of adsorption and electrocatalysis.The adsorption equilibrium of phenol on activated carbon fiber was coincident with Freundlich isotherm.A kinetic model for CODCr removal was established based on the adsorption and electrocatalysis process.The agreement of model prediction and the experimental data was well.The parameter predicted from the kinetic model showed that the adsorption process made more contribution to CODCr removal than electrocatalysis.
By combined electrocatalysis and adsorption method the degradation of wastewater containing phenol was investigated.The influences of current intensity on the removal of chemical oxygen demand（CODCr）,average current efficiency and energy consumption were studied.The results showed that high current density was favorable for removal of CODCr.Considering the average current efficiency and energy consumption,current of 0.6 A was chosen to be the suitable current intensity.Electrolyte could remarkably affect the removal of phenol.NaCl exhibited more significant promotion on CODCr removal than Na2SO4.Activated carbon fiber,based on its adsorption and electrochemical character,was used as cathode material to degrade the phenol.It was found that the removal rate of CODCr could reach 90% after 10 min treatment by the combination of adsorption and electrocatalysis.The adsorption equilibrium of phenol on activated carbon fiber was coincident with Freundlich isotherm.A kinetic model for CODCr removal was established based on the adsorption and electrocatalysis process.The agreement of model prediction and the experimental data was well.The parameter predicted from the kinetic model showed that the adsorption process made more contribution to CODCr removal than electrocatalysis.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2010年第11期2971-2977,共7页
CIESC Journal
基金
国家自然科学基金项目(20976162
20906079)
浙江省自然科学基金项目(Y4080335)
浙江工商大学青年人才基金项目(Q09-5)~~
关键词
电催化
活性炭纤维
吸附
苯酚
动力学
electrocatalysis
activated carbon fiber
adsorption
phenol
kinetics
