期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Ag-Cu双金属纳米粒子的制备及其电催化性质 被引量：1

Preparation and Electrocatalysis of Silver-Copper Bimetallic Nanoparticles
下载PDF
导出
摘要 在β-环糊精(β-CD)溶液中,用柠檬酸三钠还原AgNO3制备了银纳米粒子,以银纳米粒子为晶种,用水合肼还原CuSO4制备Ag-Cu双金属纳米粒子,并用紫外—可见光谱(Uv-vis)、透射电子显微镜(TEM)、选区电子衍射(SAED)、X射线粉末衍射(XRD)等表征所制备的Ag-Cu双金属纳米粒子。用循环伏安法对Ag-Cu双金属纳米粒子修饰的玻碳电极的电化学性能进行测试,实验结果表明Ag-Cu双金属纳米粒子对H2O2的电化学氧化基本没有催化作用。 Silver nanoparticles were generated in β-CD solutions in which trisodium citrate serves as the reducing agent.Then silver-copper bimetallic nanoparticles were formed by using a simple silver seed-mediated growth method.Uv-visible spectra（Uv-vis）,transmission electronic microscopy（TEM）,X-ray diffraction（XRD） and selected area electron diffraction（SAED） were used to characterize the obtained silver-copper bimetallic nanoparticles.The electrochemical performance of Ag-Cu bimetallic nanoparticles / glassy carbon（GC）electrode was investigated by cyclic voltammetry method.The results showed that the Ag-Cu / GC electrode did not have electrocatalytic activity for H2O2 oxidation.
作者 李中春 陈旭红 赵兴红 赵祯怡
机构地区 江苏技术师范学院江苏省贵金属深加工技术及应用重点建设实验室 江苏技术师范学院东方学院
出处 《江苏技术师范学院学报》 2010年第9期49-53,共5页 Journal of Jiangsu Teachers University of Technology
基金 江苏省普通高校自然科学研究计划资助项目(08KJB150007) 江苏省贵金属深加工技术及应用重点建设实验室开放研究课题基金资助项目(SYGK0712) 江苏技术师范学院青年基金资助项目(KYZ08023)
关键词 双金属 制备 电催化 bimetal preparation electrocatalysis
分类号 O614.122 [理学—无机化学]
  • 相关文献

参考文献28

  • 1Wang A Q, Hsieh Y, Chen Y F, et al. Au-Ag alloy nanoparticle as catalyst for CO oxidation: Effect of Si/Al ratio of mesoporous support[J]. J Catal, 2006, 237 ( 1 ): 197-206.
  • 2Liu X Y, Wang A Q, Wang X D, et al. Au-Cu Alloy nanoparticles confined in SBA-15 as a highly efficient calalyst for CO oxidation[J]. Chem Comm,2008, (27): 3 187-3 189.
  • 3Chen L, Zhao W, Jiao W, et al. Characterization of Ag/Pt core-shell nanoparticles by UV-vis absorption, resonance light-scattering techniques[J]. Speetroehim Acta A, 2007, 68 : 484-490.
  • 4Wu S P, Ni J, Jiao L, et al. Preparation of ultra-fine copper-nickel bimelallie powders with hydrothermal-reduetion melhod[J]. Mater Chem Phys, 2007, 105:71-75.
  • 5Gareia-Gutierrez D I, Gutierrez-Wing C E, Giovanetti L, et al. Temperature effect on the synthesis of Au-Pt bimetallic nanoparticles[J]. J Phys Chem B, 2005, 109 (9): 3 813-3 821.
  • 6Tsuji M, Miyamae N, Lim S, et al. Crystal structures and growth mechanisms of Au@Ag core-shell nanoparticles prepared by the microwave-polyol method[J]. Cryst Growth Des, 2006, 6 (8): 1 801-1 807.
  • 7Tsuji M, Nishio M, Jiang P, et al. Role of chloride ions in the formation of Au@Ag core-shell nanocrystal structures by using a microwave-polyol method[J]. Colloids Surf A, 2008, 317 (1-3): 247-255.
  • 8Bakshii M S, Sharma P, Banipal T S. Au and Au-Ag bimetallic nanoparticles synthesized by using 12-3-12 cationic Gemini surfaclant as template[J]. Mater Lett, 2007, 61:5 004-5 009.
  • 9Zou X Q, Ying E B, Dong S J. Preparation of novel silver-gold bimetallic nanostructures by seeding with silver nanoplates and application in surface-enhanced Raman scattering[J]. J Colloid Interface Sci, 2007, 306 (2): 307-315.
  • 10Guo S J, Wang L, Wang W, et al. Bifunetional Au@Pt hybrid nanorods[J]. J Colloid Interface Sci, 2007, 315:363-368.

同被引文献22

  • 1冯瑞香,曹余良,艾新平,杨汉西.AgNi合金作为直接硼氢化物燃料电池的阳极催化剂[J].物理化学学报,2007,23(6):932-934. 被引量：11
  • 2M.E.Indig,R.N.Snyder,An interesting anodic fuel(1),J. Electrochem.Soc,109(11),1104(1962).
  • 3S.C.Amendola,P.Onnerud,M.T.Kelly,P.J.Petillo, S.L.Sharp-Goldman,M.Binder,A novel high power density borohydride-air cell,J.Power Sources,84(1), 130(1999).
  • 4S.M.Lee,J.H.Kim,H.H.Lee,P.S.Lee,J.Y.Lee,The Characterization of an alkaline fuel cell that uses hydrogen storage alloys,J.Electrochem.Soc,149(5),A603(2002).
  • 5WANG Yonggang,XIA Yongyao,A direct borohydride fuel cell using MnO_2-catalyzed cathode and hydrogen storage alloy anode,Electrochem.Commun.,8(11), 1775(2006).
  • 6N.A.Choudhury,R.K.Raman,S.Sampath,A.K.Shukla, An alkaline direct borohydride fuel cell with hydrogen peroxide as oxidant,J.Power Sources,143(1),1(2005).
  • 7G.H.Miley,N.Luo,J.Mather,R.Burton,G.Hawkins, L.F.Gu,E.Byrd,R.Gimlin,P.J.Shrestha,G.Benavides, J.Laystrom,D.Carroll,Direct NaBH4/H2O2 fuel cells,J. Power Sources,165(2),509(2007).
  • 8R.K.Raman,N.A.Choudhury,A.K.Shukla,A 28-W portable direct borohydride-hydrogen peroxide fuel-cell stack,Electrochem.Solid State Lett.,7(12),A488(2004).
  • 9R.R.Bessette,J.M.Cichon,Dischert.,E.G.Dow,A study of cathode catalysis for the aluminium/hydrogen peroxide semi-fuel cell,J.Power Sources,80(1),248(1999).
  • 10Russell R.Bessette,Maria G.Medeiros,Charles J.Patrissi, Craig M.Deschenes Christopher N.LaFratta,Development and characterization of a novel carbon fiber based cathode for semi-fuel cell applications,J.Power Sources, 96(1),240(2001).

引证文献1

二级引证文献5

江苏技术师范学院学报
2010年 第9期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部