摘要
以二氯乙醚、甲胺水溶液和液碱为主要原料合成了Ｎ甲基吗啉。在常压下，温度控制在８５℃，反应时间４～５ｈ，原料二氯乙醚、甲胺、碱（ＮａＯＨ）的摩尔比１．２∶１∶２。得到的产物经过精馏提纯，可得到纯度为９５％以上的产品，精馏的收率可达９４％。
N Methyl morpholine is synthesized starting from dichloroethyl ether and methylamine and sodium hydroxide.The optimum reaction conditions are as follows:the reaction temperature is 85,the reaction time is 45 hours,the molar ratio of ClCH\-2CH\-2OCH\-2CH\-2Cl to CH\-3NH\-2 to NaOH is 1.212.The reaction mixture obtained is purified by rectifying.The yield of the product is 94% and the purity is over 95%.\=
出处
《精细化工》
EI
CAS
CSCD
北大核心
1999年第3期63-64,共2页
Fine Chemicals
关键词
甲基吗啉
合成
精馏
工艺
N methyl morpholine
synthesis
rectification\=
