钍与双希夫碱配合物的合成与表征

Synthesis and Characterization of DbsalophdnH2 and DbsalenH2 Th() Complexes

由二溴水杨醛缩二胺与硝酸钍合成了两种新的固体配合物，并对合成的配合物进行了元素分析和红外光谱、紫外光谱、差热热重、摩尔电导分析，确定了配合物的组成均为ＴｈＬ（ＮＯ３）４·Ｈ２Ｏ（Ｌ为配体）。

Two new solid complexes (NO3)2H2O and (NO3)2H2O ophenylenebis(3,5dibromosalicylideneimine), DbsalenH2=N,Nethylenebis(3,5dibromosalicylideneimine)] were synthesized by the reaction of thorium nitrate with DbsalophdnH2 or DbsalenH2. These complexes were characterized by elemental analysis, DTA TG, IR, UV, molar conductance analysis. The possible structure and some properties of the complexes were studied.