摘要
采用溅射-置换(SD)法在导电玻璃(FTO)基底上制备了染料敏化太阳能电池(DSSC)对电极SD-Pt/FTO.形貌表征显示,和热解法(PY)所获得的对电极(PY-Pt/FTO)相比,SD法获得的对电极SD-Pt/FTO上Pt颗粒分散性显著改善.光电流-光电压特性曲线测试表明,以SD-Pt/FTO为DSSC对电极的光电转化效率比以PY-Pt/FTO为DSSC对电极的提高了16.5%.DSSC电池性能改善与SD-Pt/FTO对电极具有较低的电阻和由Pt颗粒分散性改善引起催化性能改善密切相关.
A Pt/FTO electrode for dye-sensitized solar cells (DSSC) was prepared by the sputtering (Cu) - displacement (Pt) (SD) method on a conductive glass (FTO) substrate (SD-Pt/FTO). Morphological characterization revealed that the dispersion of Pt particles on the SD-Pt/FTO electrode was significantly improved in comparison with the PY-Pt/FTO electrode prepared by the pyrolysis of Pt salts (PY). Optical current-voltage curves showed that the photoelectric conversion efficiency of DSSC with a SD-Pt/FTO counter electrode increased by 16.5% relative to that with a PY-Pt/ FTO counter electrode. The improvement of DSSC performance with the SD-Pt/FTO electrode is due to its lower electric resistance, and good catalysis resulting from the improved dispersion of Pt particles in the SD process compared with the PY process.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
2010年第11期2957-2961,共5页
Acta Physico-Chimica Sinica
基金
国家自然科学基金(20806096)
重庆大学211工程三期创新人才培养建设计划研究生开放实验室支持项目(S-09013)~~
关键词
染料敏化太阳能电池
电极
溅射
铂
Dye-sensitized solar cell
Electrode
Sputtering
Pt