摘要
分别测定了在340~360K范围内乙醇和氯化镁饱和乙醇溶液的蒸气压与温度对应数据;根据热力学原理本文推导出蒸气压法和沸点升高法精确计算乙醇活度的方程式;用本文导出的方程式和教科书中常见的方程式处理实验数据,结果有所差别。
The vapor pressure of alcohol and saturated solution of magnesium chloride in alcohol was respectively measured at the different temperature(340K to 360K).According to the principle of thermodynamics,some equations for calculating the activity from vapor pressure or boiling point were derived.There are a few differences between the results calculated by the different equations.
出处
《实验室研究与探索》
CAS
1999年第3期40-43,共4页
Research and Exploration In Laboratory
基金
国家纺织教育总会面向21世纪教改基金
关键词
饱和溶液
蒸气压
活度
蒸发热
氯化镁
乙醇
saturated solution
vapor pressure
activity
enthalpy of vaporization
magnesium chloride
alcohol