NaCl-CaCl_2盐水低温拉曼光谱特征及在包裹体分析中的应用

Cryogenic Raman Spectroscopic Characteristics of NaCl-H_2O,CaCl_2-H_2O and NaCl-CaCl_2-H_2O: Application to Analysis of Fluid Inclusions

准确判断流体包裹体的含盐类型及盐度的定量计算一直是流体包裹体研究的重要内容。传统测试包裹体盐度的方法主要是冷冻法,为了克服冷冻相变不易观测等缺点,作者利用激光拉曼光谱在低温(-180℃)下测试了NaCl-H2O,CaCl2-H2O及NaCl-CaCl2-H2O体系溶液图谱,发现在低温(-180℃)下NaCl.2H2O和CaCl2.6H2O两水合物在3 420和3 432 cm-1处峰值与冰晶的3 092 cm-1峰值比和盐度之间有很好的线性关系,建立了流体包裹体盐度的工作曲线。该方法用人工合成碳酸盐岩含烃盐水包裹体进行了验证,并在东营凹陷丰深6井石英盐水包裹体进行了实例分析。结果表明,低温拉曼光谱技术不仅可识别盐的类型,也可确定盐度,应用效果良好。

Accurately diagnosing the types of the salt and calculating the salinity quantitatively are the significant content of fluid inclusions.The traditional method of testing fluid inclusions salinity is cooling. To overcome the difficulty for observing freezing phase transition,the authors tested the spectrum of NaCl-H2O,CaCl2-H2O and NaCl-CaCl2-H2O systems at180 ℃ by laser Raman spectroscopy.The result demonstrates that the ratio of peak values has linear relationship with salinity.Calibration curves were established by typical ratio of hydro-halite at 3 420 cm-1 to the ice at 3 092 cm-1,and the ratio of antarcticite at 3 432 cm-1 to the ice at 3 092 cm-1.The calibration curves have very high correlation coefficient.This method is verified by synthetic hydrocarbonbearing aqueous fluid inclusions and quartz aqueous fluid inclusions of well Fengshen 6 in Dongying sag.The results of the authors＇ experiments show that cryogenic Raman spectroscopy can not only identify the types of the salts but also determine the salinity effectively in fluid inclusions.