图解迭代法求解配合物稳定常数和吸光系数

Determination of Stability Constants and Absorption Coefficients of Coordination Compound by Iterative Graphic Method

提出了一种光度法同时测定最大配位数为2的配合物各级稳定常数和吸光系数的图解迭代方法。该法主要基于平均吸光系数极限值及其渐近线交点的性质。使用了2种配合物体系用于计算,计算结果与真值一致。

An iterative graphic method for determining stability constants and absorption coefficients of coordination compound whose maximum coordination is 2 by spectrometry was presented.This method used the properties of limiting values of average absorption coefficients and intersection point of two asymptotes.The imaginary data of two coordination compounds were used for calculation,and their results can agree with preset values.