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Preparation of TiO2 and SiC Films from Their Precursors Using Electrospraying

Preparation of TiO_2 and SiC Films from Their Precursors Using Electrospraying
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摘要 Titanium dioxide(TiO2) films were prepared by cone - jet mode electrospraying a titanium ethoxideprecursor solution onto a silicon substrate.The effects of spraying time,substrate temperature and aging on thesurface morphology of the films prepared were studied.Thin films obtained after spraying for 600 s were aged atroom temperature to form a porous TiO2 network with pores in the size range of 100 - 500 nm.Thicker filmswere prepared by spraying for 3 000 s,but these cracked on drying although it can be concluded that films pre-pared using a higher substrate temperature were denser.By this method,SiC coating was also prepared on anAl2O3 substrate using polysilane as a precursor.The result implies the potential of an industrial production ofdye sensitized solar cells by electrospraying technique. Titanium dioxide(TiO2 )films were prepared by cone- jet mode electrospraying a titanium ethoxide precursor solution onto a silicon substrate. The effects of spraying time, substrate temperature and aging on the surface morphology of the films prepared were studied. Thin films obtained after spraying for 600 s were aged at room temperature to form a porous TiO2 network with pores in the size range of 100 -500 nm. Thicker films were prepared by spraying for 3 000 s, but these cracked on drying although it can be concluded that films prepared using a higher substrate temperature were denser. By this method, SiC coating was also prepared on an Al2O3 substrate using polysilane as a precursor. The result implies the potential of an industrial production of dye sensitized solar cells by electrospraying technique.
作者 时方晓
出处 《沈阳建筑大学学报(自然科学版)》 CAS 北大核心 2010年第6期1166-1171,共6页 Journal of Shenyang Jianzhu University:Natural Science
基金 supported by the Science Foun-dation of Educational Commission and Provincial Key Laboratory Program of Liaoning Province of China(Grant No.2008593 and CL-200902)~~
关键词 ELECTROSPRAYING cone-jet mode porous TiO2 films SiC coating surface morphology electrospraying cone-jet mode porous TiO2 films SiC coating surface morphology
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