摘要
制备了一些氯酞菁金属配合物，研究了它们与多氟醇盐的反应．结果表明，该反应可以方便地在氯酞菁环上引入多氟烷氧基．借此合成了一些多氟烷氧基取代金属酞菁配合物．产物经分离提纯后，用元素分析、ＩＲ、ＵＶ－Ｖｉｓ及１９ＦＮＭＲ谱进行了表征，并观测了多氟烷氧基的引入对其脂溶性。
The preparation of some chlorophthalocyanines and the reactions of them with sodium polyfluoroalkoxide were reported in this paper. Some polyfluoroalkoxy chlorophthalocyanines have been obtained by this way, and characterized by elementary analysis, IR, UVVis, 19F NMR spectra after purification. The effects of introduction of polyfluoroalkoxy group in the ring on the solubility, thermodynamic stability and electronic spectra were also discussed.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1999年第3期403-406,共4页
Chemical Journal of Chinese Universities
基金
湖北省自然科学基金
关键词
多氟金属酞菁
合成
脂溶性
热力学
酞菁配合物
Polyfluoroalkoxy chlorophthalocyanine, Synthesis, Liposolubility, Thermodynamic stability
