摘要
With the aid of the critical size of colloidal cluster, the critical volume fraction of phase transition of colloidal system is determined by the principle of entropy maximum and Carnahan-Starling （CS） state equation in this paper. In our discussion, no parameter is introduced externally, and our results are in good agreement with the experimental results.
With the aid of the critical size of colloidal cluster, the critical volume fraction of phase transition of colloidal system is determined by the principle of entropy maximum and Carnahan-Starling （CS） state equation in this paper. In our discussion, no parameter is introduced externally, and our results are in good agreement with the experimental results.
基金
Project supported by the National Natural Science Foundation of China (Grant Nos. 10375024 and 10775018)
the Science Foundation of Hunan Educational Committee of China (Grant Nos. 08B028 and 06B057)
the Natural Science Foundation of Hunan Province of China (Grant No. 08jj6043)
