5-硝基水杨醛缩氨基氧化吡啶配合物合成研究

Synthesis and Properties of 5-nitrosalicylaldehyde Condensation of 2-amino N-oxide Pyridine and Its Metal Complexity

在温和条件下由5-硝基水杨醛和氨基氧化吡啶缩合形成了Schiff碱配体,将其与铜(Ⅱ)、镍(Ⅱ)、锌(Ⅱ)、钴(Ⅱ)作用合成了几种新的配合物。通过红外光谱、紫外-可见光谱、电导率和熔点等方法对配合物的组成、结构进行了表征,并通过生物活性检测了它们的抑菌作用。

HBsalapm(HBsalapm = HL = 5-nitrosalicylaldehyde condensation 2-amino N-oxide pyridine)and their complexes with metals(M = Cu2+、Ni2+、Co2+Zn2+)were synthesized respectively.The compositions and structures of the complexes are characterized by IR,UV-Vis,electric conductivity and melting point etc.