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δ-[Zn(CH_3COO)_2]:一种具有lvt拓扑结构的无水醋酸锌

δ-[Zn(CH_3COO)_2]:An Anhydrous Zinc Acetate with lvt Topology
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摘要 利用溶剂热除水的方法,在冰醋酸中,将二水醋酸锌脱水制备了一种新型的无水醋酸锌.X射线单晶衍射分析揭示出化合物1具有一个四面体形的金属中心,它与顺-反醋酸根阴离子相连接,形成一种三维四连接的网状lvt拓扑结构. A novel anhydrous zinc acetate,(δ-[Zn(CH3COO)2](1),was readily prepared by solvothermal dehydration of zinc acetate dihydrate in glacial acetic acid.X-ray single-crystal analysis reveals that compound 1 consists of tetrahedral metal centers,which are linked by the syn-anti acetato anions forming a three-dimensional(3D) 4-connected net of lvt topology.
作者 刘葵
机构地区 辽宁大学出版社
出处 《辽宁大学学报(自然科学版)》 CAS 2010年第4期310-313,共4页 Journal of Liaoning University:Natural Sciences Edition
关键词 无水醋酸锌 单晶结构 溶剂热合成 lvt拓扑结构 Anhydrous zinc acetate Single-crystal structure Solvothermal synthesis Lvt topology
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参考文献11

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