摘要
Pure CoAPO-36 crystal grains were synthesized by hydrothermal reaction. Porous α-Al2O3, stainless steel and K2Ti6O13 supported CoAPO-36 films were fabricated using in situ crystallization for the first time. SEM images and XRD measurements demonstrate that a continuous CoAPO-36 film was obtained on the K2Ti6O13 substrate. Diffuse reflectance UV-Vis spectra indicate that Co2+ has been incorporated into the ATS framework. Both CoAPO-36 crystal grains and the K2Ti6O13 supported CoAPO-36 film exhibit satisfactory catalytic activities for the oxidation of cyclohexane.
Pure CoAPO-36 crystal grains were synthesized by hydrothermal reaction. Porous α-Al2O3, stainless steel and K2Ti6O13 supported CoAPO-36 films were fabricated using in situ crystallization for the first time. SEM images and XRD measurements demonstrate that a continuous CoAPO-36 film was obtained on the K2Ti6O13 substrate. Diffuse reflectance UV-Vis spectra indicate that Co^2＋ has been incorporated into the ATS framework. Both CoAPO-36 crystal grains and the K2Ti6O13 supported CoAPO-36 film exhibit satisfactory catalytic activities for the oxidation of cyclohexane.
基金
supported by the National Natural Science Foundation of China (20636030, 20776100 and 20776108)
