摘要
对ＴＸ－１００、正戊醇、正己醇、正庚醇、正辛醇及辛烷形成的反相微乳液用ＥＳＲ自旋标记方法进行了研究，结果认为反相微乳液的形成过程伴随着表面活性剂链排列的变化，在加入水量较少时栅状区域的表面活性剂链排列拥挤，进一步的水化作用使其排列疏松。而疏水性强的探针则表明水化作用渗透到了反相微乳液的疏水区域。
The associated structure of TX-100 reverse microemulsion formed by octane and different cosurfactants such as petanol,hexanol,heptanol and octanol is studied.It's shown that surfactant chains packed closely as water addition are small,and it becomes loose with hydration process continue.Results labeled by hydrophilic probe show that hydration action permeates into hydrophilic region of reverse microemulsion.
出处
《化学研究》
CAS
1999年第1期25-28,43,共5页
Chemical Research
基金
国家攀登计划资助项目
