摘要
本文开发了从烯烃生产环氧烷烃,二氧化碳合成碳酸二甲酯联产二元醇,以绿色化学原料碳酸二甲酯代替剧毒的光气,开发了碳酸甲乙(丙、丁、戊、己、辛酯)、二乙(丙、丁、戊、己、辛)酯、二苯酯、呋喃唑酮、碳酰肼、苯胺基甲酸甲酯、苄胺基甲酸甲酯、对苯二胺二甲酸甲酯、间羟苯胺基甲酸甲酯、间甲苯胺基甲酸甲酯、二胺基甲酸甲酯二苯甲烷、己二胺二甲酸甲酯、烷基胺甲酸甲酯、肼基甲酸甲酯、嘧黄隆、甲黄隆、氯黄隆、异氰酸酯、聚氨酯、聚碳酸酯等一系列绿色清洁生产新工艺,间接实现了二氧化碳替代剧毒的光气,形成了具有中国特色的二氧化碳的绿色高新精细化工产业链,可建设成为低碳生态产业园。
In this paper,it is studied that how to synthesize dimethyl carbonate(DMC) with carbon dioxide as material and diols as co-productions,as well as how to product epoxy alkanes from olefins.And it is worth mentioning that DMC is a kind of environment-friendly chemical materials. Besides,DMC,instead of toxic phosgene,is used to develop a series of new clean technologies in this article,such as the production process of ethyl(propyl/butyl/pentyl/hexyl/oxtyl)-methyl/ diethyl/dipropyl/dibutyl/dipentyl/dihexyl/dioxtyl carbonates,furazolidone,hydrazine carbonate,methyl phenylamine/ benzylamine carbamates,dimethyl p-phenylenediamine dicarbamate,methyl m-hydroxyl-amine/m-toluidine carbamates,dimethyl 4,4'-diphenyl methane/ dimethyl 1,6-hexanediamine dicarbamates,alkylamine methyl carbamate,methyl hydrazine,sulfometuron,metsulfuron-methyl,chlorimuron-ethyl etc.This new production technology which made use of carbon dioxide indirectly and replaced the toxic phosgene can promote optimization of chemical industry structure and shape a Green High-tech Fine Chemical Industry Eco-system for producing a series of fine chemical products with carbon dioxide. All the researches discussed above are significant.By the investigations,not only the industrial structure is optimized,but energy conservation also is promoted.
出处
《合成化学》
CAS
CSCD
北大核心
2010年第B09期7-17,共11页
Chinese Journal of Synthetic Chemistry
基金
国家自然科学基金资助项目(20376024)
国家863计划资助项目(2006AA030204)
关键词
二氧化碳
碳酸二甲酯
清洁生产
绿色化工产业链
低碳生态产业园
Dimethyl carbonate
carbonylation reaction
clean process
replacing phosgene
green chemical eco-industry system.