摘要
The title compound(13,27-dichloro-3,6,9,17,20,23-hexaazatricyclo-[23.3.1.111,15]-triaconta-l(29),2,9,11,13,15(30),16,23,25,27-decaene-29,30-diol-N3,N6,N9,O29,O30)-bis(nitrato-O,O)-Europium(Ⅲ) nitrate was prepared and characterized by elemental analysis,infrared spectra,electrospray mass spectrum and X-ray diffraction,respectively.The crystal of the complex crystallizes in the monoclinic system,space group C2/c with a=2.3737(2) nm,b=14.333(1) nm,c=19.388(2) nm,β = 91.804(1)°,Mr= 850.4,V= 6.5929(8) nm3,R= 0.0333,wR= 0.0936.At room temperature,excitation of the title complex gives rise to the characteristic luminescent emissions of the Eu3+ ion.
The title compound(13,27-dichloro-3,6,9,17,20,23-hexaazatricyclo-[23.3.1.111,15]-triaconta-l(29),2,9,11,13,15(30),16,23,25,27-decaene-29,30-diol-N3,N6,N9,O29,O30)-bis(nitrato-O,O)-Europium(Ⅲ) nitrate was prepared and characterized by elemental analysis,infrared spectra,electrospray mass spectrum and X-ray diffraction,respectively.The crystal of the complex crystallizes in the monoclinic system,space group C2/c with a=2.3737(2) nm,b=14.333(1) nm,c=19.388(2) nm,β = 91.804(1)°,Mr= 850.4,V= 6.5929(8) nm3,R= 0.0333,wR= 0.0936.At room temperature,excitation of the title complex gives rise to the characteristic luminescent emissions of the Eu3+ ion.
基金
Funded by the Natural Science Founation of Hubei Province (No.2005ABA021)