摘要
The title compound（13,27-dichloro-3,6,9,17,20,23-hexaazatricyclo-[23.3.1.111,15]-triaconta-l（29）,2,9,11,13,15（30）,16,23,25,27-decaene-29,30-diol-N3,N6,N9,O29,O30）-bis（nitrato-O,O）-Europium（Ⅲ） nitrate was prepared and characterized by elemental analysis,infrared spectra,electrospray mass spectrum and X-ray diffraction,respectively.The crystal of the complex crystallizes in the monoclinic system,space group C2/c with a=2.3737（2） nm,b=14.333（1） nm,c=19.388（2） nm,β = 91.804（1）°,Mr= 850.4,V= 6.5929（8） nm3,R= 0.0333,wR= 0.0936.At room temperature,excitation of the title complex gives rise to the characteristic luminescent emissions of the Eu3＋ ion.
The title compound（13,27-dichloro-3,6,9,17,20,23-hexaazatricyclo-[23.3.1.111,15]-triaconta-l（29）,2,9,11,13,15（30）,16,23,25,27-decaene-29,30-diol-N3,N6,N9,O29,O30）-bis（nitrato-O,O）-Europium（Ⅲ） nitrate was prepared and characterized by elemental analysis,infrared spectra,electrospray mass spectrum and X-ray diffraction,respectively.The crystal of the complex crystallizes in the monoclinic system,space group C2/c with a=2.3737（2） nm,b=14.333（1） nm,c=19.388（2） nm,β = 91.804（1）°,Mr= 850.4,V= 6.5929（8） nm3,R= 0.0333,wR= 0.0936.At room temperature,excitation of the title complex gives rise to the characteristic luminescent emissions of the Eu3＋ ion.
基金
Funded by the Natural Science Founation of Hubei Province (No.2005ABA021)
