摘要
通过Ritter反应合成弱阴离子型疏水单体丙烯酰胺基十一烷基酸(C11AM).以丙烯酰胺(AM)、甲基丙烯酰氧乙基三甲基氯化铵(DMC)和丙烯酰胺基十一烷基酸(C11AM)为原料,在水介质中合成新型疏水缔合聚两性电解质AM/DMC/C11AM.利用1H NMR确证了疏水单体和共聚产物的分子结构.流变性和芘荧光探针的研究结果表明,AM/DMC/C11AM系列疏水缔合聚两性电解质由于兼具疏水缔合性质和反聚电解质效应,使其具有较好的耐盐性能.
A series of hydrophobically associating polyampholytes[poly（AM/DMC/C11AM） ]was synthesized by the free radical polymerization in water.In this process,C11 AM was synthesized by Ritter reaction,and used to copolymerize with acrylamide（AM） and [2-（methacryloyloxy） ethyl] trimethylammonium chloride.The structure of C11AM and poly（AM/DMC/C11 AM） were confirmed by 1 H NMR.Moreover,the rheology measurement and fluorescent characterization show that poly（AM/DMC/C11AM） possessed both of the hydro-phobic association and antipolyelectrolyte behavior,which resulted in the super salt-resistance of the obtained polymers.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2010年第11期2308-2312,共5页
Chemical Journal of Chinese Universities
基金
吉林省科技发展计划项目(批准号:20096023)
吉林省与中国科学院科技合作资金项目(批准号:2009SYHZ0027)资助
关键词
阴离子疏水单体
疏水缔合聚两性电解质
疏水缔合
反聚电解质效应
抗盐性
Anionic hydrophobic monomer
Hydrophobically associating polyampholyte
Hydrophobic associ-ation
Anti-polyelectrolyte behavior
Salt-resistance
