期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

新型1,4,5,8-萘酰亚胺类衍生物的合成 被引量：1

Synthesis of Novel 1,4,5,8-Naphthalimide Derivatives
下载PDF
导出
摘要 以1,4,5,8-萘四甲酸二酐(1)和2-乙基己胺(2)为原料,设计并合成了3种新型的1,4,5,8-萘酰亚胺类衍生物,其结构经1H NMR,IR和MS表征。中间体N-(2-乙基己基)-萘-1,8-二甲酸单酐-4,5-单甲酰亚胺的最佳反应条件为:19.7 mmol,n(1)∶n(2)=1.1∶1.0,以醋酸锌为催化剂,在DMF(20 mL)中于140℃反应15h,收率25%。 Three novel 1,4,5,8-naphthalimide derivatives were designed and synthesized from 1,4,5,8-naphthalenetetracarboxylic dianhydride（1） and 2-ethylhexan-1-amine（2）.The structures were characterized by 1H NMR,IR and MS.The optimum reaction conditions of synthesizing intermediate N-（2-ethylhexyl）-1,4,5,8-naphthalenetetracarboxylic-1,8-anhydride-4,5-imide were as follows： 1 was 9.7 mmol;n（1） ∶n（2） was 1.1 ∶1.0;Zinc acetate was used as the catalyst and the reaction carried out in DMF（20 mL） at 140 ℃ for 15 h.The yield was 25% under the optimum reaction conditions.
作者 刘万定 吕良飞 汪维 陈梅 唐超 吴杰颖
机构地区 安徽大学化学化工学院
出处 《合成化学》 CAS CSCD 北大核心 2010年第6期709-711,共3页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(20771001) 安徽省教育厅重点科研项目(KJ2010A030)
关键词 2-乙基己胺 萘酰亚胺 衍生物 合成 2-ethylhexan-1-amine naphthalimide derivative synthesis
分类号 O625.63 [理学—有机化学] O621.3 [理学—有机化学]
  • 相关文献

参考文献8

  • 1Ganesan P,Yang X N,Sudholter E J R.Tetrahedral n-type materials:Efficient quenching of the excitation of p-type polymers in amorphous films[J].J Am Chem Soc,2005,127(42):14530-14531.
  • 2Hoppe H,Sariciftci N S.Conjugated polymer-based organic solar cells[J].J Mater Res,2004,19:1924-1945.
  • 3Kao C C,Lin P,Yan J Y,et al.Solid-state structure of the naphthalene-based n-type semiconductors and performance improved with mo-based source/drain electrodes[J].Synthetic Matels,2008,158(7):299-305.
  • 4Ma B Q,Mulfort K L,Hupp J T.Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions[J].Inorg Chem,2005,44(14):4912-4914.
  • 5Mulfort K L,Hupp J T.Chemical reduction of matal-organic framework materials as a method to enhance gas uptake and binding[J].J Am Chem Soc,2007,129(31):9604-9605.
  • 6Pantos G D,Pengo P,Sanders J K M.Hydrogen-bonded helical organic nanotubes[J].Angew Chem Int Ed,2007,46:194-197.
  • 7Chu Y,Sorey S,Hoffman D W,et al.Structural characterization of a rigidified threading bisintercalator[J].J Am Chem Soc,2007,129(5):1304-1311.
  • 8孔繁蕾,王兰青,胡新华,陶志明,王晓青,曹维群,董浴.2—氨基嘧啶类系列化合物的合成[J].化学世界,1991,32(6):254-257. 被引量：19

共引文献18

同被引文献12

  • 1Ganesan P, Yang X N, Joachim L. Tetrahedral n-type materials: efficient quenching of the excitation of p-type polymers in amorphous films[ J ]. J Am Chem Soc ,2005,127 (42) :14530-14531.
  • 2Aaron S L, Patrick J B. Uhrafast molecular logic gate based on optical switching between two 10ng-lived radical ion pair states[ J]. J Am Chem Soc,2001,123 (10) :2440-2441.
  • 3Kao C C, Lin P, Yan J Y, et al. Solid-state structure of the naphthalene-based n-type semiconductors and performance improved with mo-based source/drain electrodes[ J ]. Synthetic Matels ,2008,158 (7) :299-305.
  • 4Pantos G D, Pengo P, Sanders J K M. Hydrogen-bonded helical organic nanotubes [ J ]. Angew Chem Int Ed,2007, 46(1/2) : 194-197.
  • 5Chu Y, Sorey S, Hoffman D W, et al. Structural characterization of a rigidified threading bisintercalator[ J]. J Am Chem Soe,2007,129 ( 5 ) : 1304-1311.
  • 6Wu A B, Xu Y F. Novel naphthalimide derivatives as potential apoptosis-inducing agents: design, synthesis and biological evaluation [ J ]. Eur J Med Chem,2009,44 ( 11 ) :4674-4680.
  • 7Barros T C, Filho P B, Toscano V G, et al. Intramolecular excimer formation from 1,8-N-alkyldinaphthalimides [ J ]. J Photochem Photobiol A : Chem, 1995,89 (2) : 141 - 146.
  • 8Barros T C, Brochsztain S. Photophysical characterization of a 1,4,5,8- naphthalenediimide derivative [ J ]. Photochem Photobiol A : Chem, 1997,111 ( 1/2/3 ) : 97-104.
  • 9Yang J S, Liau K L, Li C Y, et al. Meta conjugation effect on the torsional motion of aminostilbenes in the photoinduced intramolecular charge-transfer state[ J ]. J Am Chem Soc ,2007,129 (43) : 13183-13192.
  • 10Hu G J, Lv L F, Lin L, et al. Design, synthesis, photoluminescence and electrochemiluminescence properties of naphthalimide derivative and its silver complex [ J ]. Dyes and Pigments,2011,89 (2) :105-110.

引证文献1

二级引证文献1

合成化学
2010年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部