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配位聚合物[Zn(phen)(H_2O)_2SO_4]_n的合成与晶体结构 被引量:1

Synthesis and Crystal Structure of a Coordination Polymer [Zn(phen)(H_2O)_2SO_4]_n
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摘要 通过扩散法得到了一个新的配位聚合物[Zn(phen)(H2O)2SO4]n[phen=邻菲啰啉]。通过X-ray单晶衍射对配合物的结构进行了表征。配合物属单斜晶系,Cc空间群,晶胞参数:a=15.1399(10),b=14.1420(10),c=6.6994(5),α=90°,β=103.458(1)°,γ=90°,V=1395.01(17)3,Z=2,μ=0.752 mm-1,R1=0.0214,wR2=0.0602。 The coordination polymer [Zn(phen)(H2O)2SO4]n [phen=1,10-phenanthroline] was synthesis by diffusion. The structure was characterized by single crystal X-ray diffraction. It crystallized in monoclinic system, Cc space group, with a=15.1399(10)A,b=14.1420(10)A,c=6.6994(5)A,α=90°,β=103.458(1)°,γ=90°,V=1395.0107)A^3,Z=2,μ=0.752mm^-1,R1=0.0214,wR2=0.0602.
出处 《广东化工》 CAS 2010年第12期3-4,12,共3页 Guangdong Chemical Industry
基金 河北省自然科学基金项目(No.B2010000223)
关键词 邻菲啰啉 晶体结构 分子双链 氢键 l,lO-phenanthroline crystal structure molecule double chains hydrogen bond
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