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Photocatalytic Activities for Water Splitting of RuO_2-loaded MGa_2O_4(M=Zn,Ni) with d^(10) Configuration

Photocatalytic Activities for Water Splitting of RuO_2-loaded MGa_2O_4(M=Zn,Ni) with d^(10) Configuration
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摘要 MGa2O4(M=Zn,Ni) rods with similar crystallinity and BET surface area were prepared via a facile template-engaged reaction.The photocatalytic activities for water splitting of RuO2-loaded MGa2O4(M=Zn,Ni) were investigated under high-pressure Hg lamp.RuO2-loaded ZnGa2O4 catalyst exhibited much higher photocatalytic activity than RuO2-loaded NiGa2O4.Factors affecting the photocatalytic activities of RuO2-loaded MGa2O4(M=Zn,Ni) were discussed.It was suggested that the electronic structure of oxide semiconductor was a predominant factor of the photocatalytic behavior for RuO2-loaded MGa2O4(M=Zn,Ni). MGa2O4(M=Zn,Ni) rods with similar crystallinity and BET surface area were prepared via a facile template-engaged reaction.The photocatalytic activities for water splitting of RuO2-loaded MGa2O4(M=Zn,Ni) were investigated under high-pressure Hg lamp.RuO2-loaded ZnGa2O4 catalyst exhibited much higher photocatalytic activity than RuO2-loaded NiGa2O4.Factors affecting the photocatalytic activities of RuO2-loaded MGa2O4(M=Zn,Ni) were discussed.It was suggested that the electronic structure of oxide semiconductor was a predominant factor of the photocatalytic behavior for RuO2-loaded MGa2O4(M=Zn,Ni).
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2010年第12期1828-1833,共6页 结构化学(英文)
基金 supported by the Natural Science Foundation of Fujian Province (No. 2009J05025) the Educational Commission of Fujian province (No. JA09051)
关键词 MGa2O4(M=Zn Ni) water splitting d10 configuration MGa2O4(M=Zn Ni) water splitting d10 configuration
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