摘要
从有离子的液体的酸的油的酸混合物(naphthenates ) 的移动系统地被调查[BMIM ] Br-AlCl3 被用来在油的 deacidification 上调查效果。试验性的结果与 AlCl3 的臼齿的比率在 323K 的温度显示出那到[BMIM ] 0.2 的 Br-AlCl3,和到白色的 IL 的集体比率 4% 上油, deacidification 率能到达 75.9% 。并且 4 h 的一反应时间是足够的达到目标。催化性能的重制度上的学习[BMIM ] Br-AlCl3 显示出在连续 catalyuic 反应使用离子的液体的可能性。
The removal of acid compounds (naphthenates) from acidic oil with ionic liquids was systematically investigated. [BMIM]Br-AlCl3 was used to investigate the effect on deacidification of oil. Experimental results showed that at a temperature of 323K with a molar ratio of AlCl3 to [BM1M]Br-AlCl3 of 0.2, and a mass ratio of IL to white oil of 4%, the deacidification rate could reach 75.9%. And a reaction time of 4 h was sufficient to achieve the goal. The study on reproducibility of catalytic performance of [BMIM]Br-AlCl3 showed the possibility of using the ionic liquid in the continuous catalytic reaction.