摘要
This paper reports that a series of Nd3＋：Er3＋：yb3＋ co-doped borosilicate glasses have been prepared and their absorption spectra measured. The J-O intensity parameters Ωk （k = 2, 4, 6）, spontaneous radiative lifetime Trad, spontaneous transition probability A, fluorescence branching ratio β and oscillator strength fed of the Nd3＋ ions at room temperature are calculated based on Judd-Ofelt （J-O） theory. The temperature dependence of the up-conversion photoluminescence characteristics in a Nd3＋：Er3＋：Yb3＋ co-doped sample is studied under a 978 nm semiconductor laser excitation, and the energy transfer mechanisms among Yb3＋, Er3＋ and Nd3＋ ions are analysed. The results show that the J-O intensity parameters Ω2 increase when the Nd3＋ concentration of the Nd3＋：Er3＋：yb3＋ co-doped borosilicate glasses increases. The possibility of spontaneous transition is small and lifetimes are long at levels of 4F5/2 and 4F3/2. The intensity of Nd3＋ emissions at 595, 691, 753, 813 and 887 nm axe markedly enhanced when the sample temperature exceeds 400 K. The reasons being the cooperation of the secondary sensitization from Era＋ to Nd3＋ and the contribution of a multi-phonon.
This paper reports that a series of Nd3＋：Er3＋：yb3＋ co-doped borosilicate glasses have been prepared and their absorption spectra measured. The J-O intensity parameters Ωk （k = 2, 4, 6）, spontaneous radiative lifetime Trad, spontaneous transition probability A, fluorescence branching ratio β and oscillator strength fed of the Nd3＋ ions at room temperature are calculated based on Judd-Ofelt （J-O） theory. The temperature dependence of the up-conversion photoluminescence characteristics in a Nd3＋：Er3＋：Yb3＋ co-doped sample is studied under a 978 nm semiconductor laser excitation, and the energy transfer mechanisms among Yb3＋, Er3＋ and Nd3＋ ions are analysed. The results show that the J-O intensity parameters Ω2 increase when the Nd3＋ concentration of the Nd3＋：Er3＋：yb3＋ co-doped borosilicate glasses increases. The possibility of spontaneous transition is small and lifetimes are long at levels of 4F5/2 and 4F3/2. The intensity of Nd3＋ emissions at 595, 691, 753, 813 and 887 nm axe markedly enhanced when the sample temperature exceeds 400 K. The reasons being the cooperation of the secondary sensitization from Era＋ to Nd3＋ and the contribution of a multi-phonon.
基金
Project supported by the Fundamental Research Funds for the Central Universities(Grant No.2010LKWL07)
the National Basic Research Program of China(Grant No.2010CB226805)
