期刊文献+

微波辅助合成纳米WO_3/TiO_2复合材料及其气敏性能 被引量:3

Microwave-assisted synthesis and gas sensitivity of WO_3/TiO_2 nanocomposites
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摘要 为改善WO3基敏感材料的气敏性能,采用微波回流法一次性合成了纳米WO3/TiO2复合材料,并研究TiO2掺杂量对用其制备的气敏元件气敏性能的影响。结果表明:此气敏元件对体积分数为100×10-6的NOx、二甲苯、H2S和丙酮气体具有较强的敏感性,掺杂w(TiO2)为20%的元件,对H2S和NOx的灵敏度分别为31.18和695.84;掺杂w(TiO2)为30%的元件,对二甲苯和丙酮的灵敏度分别为39.19和35.69。 To enhance the gas sensing property of WO3-based sensing material,WO3/TiO2 nanocomposites were one-step synthesized through a microwave returning method.Gas sensors were fabricatel from the synthesized WO3/TiO2 nanocomposites,and the effects of TiO2-doped amount on the gas sensing properties of obtained gas sensor were studied.The results show that the gas sensors have higher response to H2S,NOx,acetone and xylene of 100×10-6(volume fraction).When doped w(TiO2) is 20%,the sensitivities of the gas sensors to H2S and NOx are 31.18 and 695.84,respectively.If doped w(TiO2) is 30%,the sensitivities of the gas sensors to xylene and acetone are 39.19 and 35.69,respectively.
出处 《电子元件与材料》 CAS CSCD 北大核心 2011年第1期30-33,共4页 Electronic Components And Materials
基金 河南省教育厅自然科学基金资助项目(No.2010A430021) 郑州市科技攻关项目(No.083SGYG23143-1) 郑州轻工业学院博士启动基金资助项目(No.2008BSJJ012)
关键词 纳米WO3/TiO2复合材料 微波回流法 气敏元件 气敏性能 WO3/TiO2 nanocomposites microwave returning method gas sensor gas sensing property
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参考文献13

  • 1ROUT C S, HEGDE M, RAO C N R. H2S sensors based on tungsten oxide nanostructures [J]. Sens Actuat B, 2008, 128(2): 488-493.
  • 2SRIYUDTHSAK M, SUPOTHINA S. Humidity-insensitive and low oxygen dependence tungsten oxide gas sensors [J]. Sens Actuat B, 2006, 113: 265-271.
  • 3FARDINDOOST S, ZAD A I, RAHIMI F, et al. Pd doped WO3 films prepared by sol-gel process for hydrogen sensing [J]. Int J Hydrogen Energy, 2010, 35: 854-860.
  • 4XIA H, WANG Y, KONG F, et al. Au-doped WO3-based sensor for NO2 detection at low operating temperature [J]. Sens Actuat B, 2008, 134: 133-139.
  • 5LUO S J, FU G, CHEN H, et al. Gas sensing properties and complex impedance analysis of La2O3-added WO3 nanoparticles to VOC gases [J]. Mater Chem Phys, 2008, 109: 541-546.
  • 6SRIVASTAVA V, JAIN K. Highly sensitive NH3 sensor using Pt catalyzed silica coating over WO3 thick films [J]. Sens Actuat B, 2008, 133: 46-52.
  • 7ZENG W, LIU T M, LIU D J. Formaldehyde gas sensing property and mechanism of TiO2-Ag nanocomposite [J]. Physica B, 2010, 405(19): 4235-4239.
  • 8PARK J A, MOON J, LEE S J, et al. Structural, electrical and gas sensing properties of eletrospun TiOz nanofibers [J]. Thin Solid Films, 2010, 518(22): 6642-6645.
  • 9冯庆,王新强,刘高斌,王万录.TiO_2-WO_3复合薄膜型气敏传感器性质研究[J].真空科学与技术学报,2007,27(4):278-281. 被引量:4
  • 10尹英哲,胡明,冯有才,陈鹏,刘志刚.双层结构TiO2-WO3气敏薄膜特性的研究[J].压电与声光,2008,30(5):588-590. 被引量:3

二级参考文献39

  • 1燕姗姗,吴连弟,陈锋,张金龙.双晶型TiO_2薄膜的低温制备及表征[J].物理化学学报,2007,23(3):414-418. 被引量:13
  • 2刘作华,陶长元,刘仁龙,孙大贵,左赵宏.微波-Fenton法处理垃圾渗滤液的研究[J].压电与声光,2007,29(3):344-346. 被引量:15
  • 3FUJISHIMA A,RAO T N,TRYK D A. Titanium dioxide photocatalysis [J]. J Photoehemi Photobiol C, 2000,1(1) :1-21.
  • 4LINSEBIGLER A L, LUG Q, YATES J T. Photocatalysis on TiO2 surfaces., principles, mechanisms, and selected results[J].Chem Rev, 1995,95(3) : 735-758.
  • 5WATSON S,BEYDOUN D, SCOTT J, et al. Preparation of nanosized crystalline TiO2 particles at low temperature for photocatalysis [J]. J Nanoparticle Research,2004,6(2):193-207.
  • 6LIU A R,WANG S M,ZHAO Y R,et al. Low-temperature preparation of nanocrystalline TiO2 photocatalyst with a very large specific surface areal-J]. Mater Chem Phys,2006,99(1) :131-134.
  • 7ITO S, INOUE S, KAWADA H, et al. Low-temperature synthesis of nanometer sized crystalline TiO2 particles and Their photoinduced decomposition of formic acid [J]. J Colloid Interface Sci, 1999,216 ( 1 ) : 59-64.
  • 8UEKAWA N, KAJIWARA J, KAKEGAWA K, et al. Low Temperature synthesis and characterization of porous anatase TiO2 nanopartieles[J]. J Colloid Inter- face Sei,2002,250(2) :285-290.
  • 9MURUGAN A V, SAMUEL V, RAVI V. Synthesis of nanocrystalline anatase TiO2 by microwave hydrothermal method [J]. Mater Lett,2006,60(4) :479-480.
  • 10BALDASSARI S, KOMARNENI S, MARIANI E, et al. Microwave-hydrothermal process for the synthesis of rutile[J]. Mater Res Bull, 2005, 40 (11): 2 014- 2 020.

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同被引文献33

  • 1林贺,范新会,于灵敏,严文.紫光激发对CeO_2掺杂ZnO纳米线气敏性能的影响[J].铸造技术,2009,30(3):412-415. 被引量:2
  • 2杨彧,贾殿赠,葛炜炜,金春飞,忻新泉.低热固相反应制备无机纳米材料的方法[J].无机化学学报,2004,20(8):881-888. 被引量:41
  • 3娄向东,贾晓华,徐甲强.纳米LaFeO_3的制备及H_2S气敏性能研究[J].传感技术学报,2006,19(6):2491-2494. 被引量:4
  • 4康明阳,曹传宝,许兴燕,廖波.熔盐法制备WO_3一维纳米结构及其气敏性能研究[J].科学通报,2007,52(21):2474-2476. 被引量:4
  • 5QIN J,CUI Z D,YANG X J,et al.Synthesis of three-dimensionally ordered macroporous La Fe O3 with enhanced methanol gas sensing properties[J].Sens Actuat B,2015,209:706-713.
  • 6BENALI A,AZIZI S,BEJAR M,et al.Structural,electrical and ethanol sensing properties of double-doping La Fe O3 perovskite oxides[J].Ceram Int,2014,40:14367-14373.
  • 7MURADE P A,SANGAWAR V S,CHAUDHARI G N,et al.Acetone gas-sensing performance of Sr-doped nanostructured La Fe O3semiconductor prepared by citrate sol-gel route[J].Curr Appl Phys,2011,11(3):451-456.
  • 8XIAO H X,XUE C,SONG P,et al.Preparation of porous La Fe O3microspheres and their gas-sensing property[J].Appl Surf Sci,2015,337(15):65-71.
  • 9TANG P S,TONG Y,CHEN H F,et al.Microwave-assisted synthesis of nanoparticulate perovskite La Fe O3 as a high active visible-light photocatalyst[J].Curr Appl Phys,2013,13:340-343.
  • 10WEN Z,ZHU L P,MEI W M.Rhombus-shaped Co3O4 nanorod arrays for high-performance gas sensor[J].Sens Actuat B,2013,186:172-179.

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