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方酸菁染料/二芳基碘鑑盐体系引发丙烯酸酯光交联反应 被引量:1

PHOTOCROSSLINKING OF ACRYLATES INITIATED BY SQUARYLIUM DYE AND DIARYLIODONIUM SALT SYSTEM
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摘要 近年来随着高新技术的迅猛发展,激光技术和光化学也随之大量应用到先进材料中,为适应这种发展需要,开发感可见光和近红外光的光敏反应体系已成为十分迫切的研究课题[1,2].方酸类染料是一类重要的功能性染料,广泛地应用于静电复印、太阳能电池和光记录材料[3]... Visible photoinitiation systems composed of squarylium cyanine dye and iodonium salt were studied in this work. Such systems possess a good thermostability and high photochemical activity. Upon irradiation, the electron transfer reaction occurs between excited dye and iodonium, leading to photobleaching of squarylium cyanine dye and cleavage of iodonium to generate active radical. The results obtained indicated that squarylium cyanine dye and iodonium salt combination can serve as a suitable visible photoinitiation system for photocrosslinking of acrylates.
出处 《感光科学与光化学》 CSCD 1999年第2期155-158,共4页 Photographic Science and Photochemistry
基金 国家自然科学基金 中国科学院感光化学所光化学开放实验室资助
关键词 电子转移 方酸菁染料 碘Weng盐 光交联 丙烯酸酯 squarylium cyanine dye, iodonium salt, electron transfer, photocrosslinking
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参考文献5

  • 1蒋松春 范如霖 等.方酸菁染料的合成[J].化学学报,1986,44:1182-1182.
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  • 3Lin T,Dyes Pigments,1997年,35卷,331页
  • 4Zhou W,J Photochem Photobiol A,1996年,96卷,25页
  • 5蒋松春,化学学报,1986年,44卷,1182页

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