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无溶剂中性条件下分子I_2或Fe(NO_3)_3·9H_2O/NaI原位生成的I_2催化醇与甲酸甲酰化反应(英文) 被引量:1

Formylation of Alcohol with Formic Acid under Solvent-Free and Neutral Conditions Catalyzed by Free I_2 or I_2 Generated in Situ from Fe(NO_3)_3·9H_2O/NaI
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摘要 Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature.I2 generated in situ from Fe(NO3)3·9H2O/NaI also catalyzed the formylation of the alcohols under solvent-free conditions.This gives a green and efficient reaction at room temperature,in which the use of toxic and corrosive molecular I2 is avoided. Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature.I2 generated in situ from Fe(NO3)3·9H2O/NaI also catalyzed the formylation of the alcohols under solvent-free conditions.This gives a green and efficient reaction at room temperature,in which the use of toxic and corrosive molecular I2 is avoided.
出处 《催化学报》 SCIE EI CAS CSCD 北大核心 2011年第1期60-64,共5页
基金 Supported by Bu-Ali Sina University and University of Kurdistan Research Councils
关键词 alcohol formic acid FORMYLATION IODINE in situ iodine SOLVENT-FREE alcohol formic acid formylation iodine in situ iodine solvent-free
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