摘要
采用聚碳硅烷(PCS)为先驱体,利用原位生长法制备SiC/Si3N4 纳米复相陶瓷,其室温弯曲强度和断裂韧性达到了637 MPa 和8.10 MPa·m 1/2。研究了材料微观结构的形成及断裂机理,指出在微观结构的形成过程中,控制SiC纳米微晶的生成和β-Si3N4 柱状晶的生长是关键,而增韧补强的主要原因在于形成了晶内型结构和长径比大(大于7.5)的Si3N4 柱状晶,从而改变了断裂机理。
A cost effective SiC/Si 3N 4 nano composite was obtained by in situ synthesis of precursor, using polycarbosilane as precursor. The results showed that the ambitious flexural strength and fracture toughness of this material had improved. The formation of this composites microstructure and the mechanism of fracture were discussed at the same time.It was important to control the formation of SiC nano crystals and the growth of rod like β Si 3N 4 grain.The formation of the intragranular structure and the rod like β Si 3N 4 grains(aspect ratio more than 7.5) was the reason for the improvement properties.
出处
《复合材料学报》
EI
CAS
CSCD
北大核心
1999年第4期13-16,共4页
Acta Materiae Compositae Sinica
关键词
先驱体
聚碳硅烷
原位生长
纳米
复相陶瓷
precursor, polycarbosilane, in situ synthesis, SiC/Si 3N 4 nano composite