摘要
介绍新近发展起来的反应性熔盐法及其在多元金属硫族化合物中温固相合成中的应用，并讨论了这类化合物的结构特征、低维性和热力学介稳性．
Molten alkali metal polychalcogenides (A 2 Q n ) as reagents and solvents (reactive fluxes) were used to synthesize multi component metal chalcogenides at intermediate temperature for the last decade. Most of the chalcogenides synthesized and crystallized from the A 2 Q n flux are in thermodynamically metastable state with low dimensional structures. In this review, we discussed the new method of solid state synthesis and structuural characteristic of the chalcogenides in detail.
出处
《材料研究学报》
EI
CAS
CSCD
北大核心
1999年第5期458-463,共6页
Chinese Journal of Materials Research
基金
国家自然科学基金
关键词
金属硫族化合物
反应性熔盐法
合成
晶体结构
multinary metal chalcogenides, reactive molten salt A 2 Q n ,solid state synthesis, crystal structure
