热动力学研究(Ⅺ)——苄基氯与醋酸钠反应的动力学研究

STUDIES ON THERMOKINETICS(XI)——THERMOKINETICS FOR THE REACTION OF BENZYL CHLORIDE WITH SODIUM ACETATE

根据不等浓度二级反应的无量纲参数法,应用热导式自动量热计,研究了苄基氯与醋酸钠在30℃时的反应动力学.测定了反应的速度常数.讨论了溶剂和催化剂对反应速度常数的影响.

On the method of dimensionless parameters of the second order reaction proposed in the previous article, the thermokinctics of the reaction of benzyl chloride with sodium acetate have been studied at 30.0C with Model RD-I conduction automatic calorimeter in this paper. The influences of solvent and catalyst on the rate constants have been also discussed.