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LaMg_(8.40)Ni_(2.34)合金的相结构和储氢性能(英文) 被引量：4

Phase Structure and Hydrogen Storage Properties of LaMg_(8.40)Ni_(2.34) Alloy
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摘要 利用真空感应熔炼和退火方法制备了LaMg8.40Ni2.34合金.采用X射线衍射(XRD)分析、扫描电镜(SEM)和压力-组成-温度(PCT)测试仪测试了合金的相组成、微观形貌和储氢性能.LaMg8.40Ni2.34合金由La2Mg17、LaMg2Ni和Mg2Ni组成,且在第一次吸放氢循环中就可以完全活化.在558K下的可逆储氢量为3.01%(质量分数),合金的PCT曲线表现出双吸氢平台,分别对应着形成的MgH2和Mg2NiH4.但是放氢曲线却只有一个平台出现,这是由MgH2和Mg2NiH4之间的协同脱氢作用产生的.LaMg8.40Ni2.34合金在吸放氢时的活化能分别为(52.4±0.4)和(59.2±0.1)kJ·mol-1,均低于Mg2Ni合金.与纯Mg和Mg2Ni合金相比,LaMg8.40Ni2.34合金具有良好的活化性能、较高的储氢性能和优良的动力学性能. The LaMg8.40Ni2.34 alloy was prepared by vacuum induction melting and subsequent heating treatment.The phase structure,morphology,and hydrogen storage properties were studied by X-ray diffraction（XRD）,scanning electron microscopy（SEM）,and pressure-composition-temperature（PCT） measurements.The LaMg8.40Ni2.34 alloy was composed of La2Mg17,LaMg2Ni,and Mg2Ni phases.The alloy can be activated in the first hydriding/dehydriding process.Its reversible hydrogen storage capacity was 3.01%（mass fraction） at 558 K.PCT curves showed two hydriding plateaus corresponding to the formation of MgH2 and Mg2NiH4 and only one dehydriding plateau,which is due to the synergetic effect of hydrogen desorption between MgH2 and Mg2NiH4.The activation energy values of LaMg8.40Ni2.34 alloy were（52.4±0.4） and（59.2±0.1） kJ·mol-1 for the hydriding and dehydriding processes,respectively,and these were lower than that of the Mg2Ni alloy.The LaMg8.40Ni2.34 alloy exhibited good activation behavior,hydrogen adsorption and desorption reversibility,and kinetic properties.
作者 李金华 刘宝忠 韩树民 扈琳 朱惜林 王明智
机构地区 燕山大学亚稳材料制备技术与科学国家重点实验室 河南理工大学材料科学与工程学院 燕山大学环境与化学工程学院
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 2011年第2期403-407,共5页 Acta Physico-Chimica Sinica
基金 supported by the National High-Tech Research and Development Program of China(863)(2007AA05Z117) National NaturalScience Foundation of China(50971112,51001043) China Postdoctoral Science Foundation(20100470990) Natural Science Foundation ofHebei Province,China (E2010001170)~~
关键词 储氢材料 La-Mg-Ni合金 压力-组成-温度曲线 多相结构 Hydrogen storage material La-Mg-Ni alloy Pressure-composition-temperature curve Multiphase structure
分类号 TG139.7 [一般工业技术—材料科学与工程]
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参考文献25

  • 1Schlapbach, L.; Zuettel, A. Nature 2001, 414, 353.
  • 2Zhu, M.; Peng, C. H.; Ouyang, L. Z.; Tong, Y. Q. J. Alloy. Compd. 2006, 426, 316.
  • 3Chio, M. D.; Ziggiotti, A.; Baricco, M. Intermetallics 2008, 16, 102.
  • 4Song, X. P.; Zhang, P. L.; Pei, P.; Liu, J.; Li, R. C.; Chen, G. L. Int. J. Hydrog. Energy 2010, 35, 8080.
  • 5Palade, P.; Sartori, S.; Maddalena, A.; Principi, G.; Lo Russo,S.; Lazarescu, M.; Schinteie, G.; Kuncser, V.; Filoti, G. J. Alloy. Compd. 2006, 415, 170.
  • 6Liu, Z. Y.; Wang, E.; Lei, Z. L. J. Alloy. Compd. 2007, 431,212.
  • 7Muthukumara, P.; Maiya, M. P.; Murthy, S. S.; Vijay, R.; Sundaresan, R. J. Alloy. Compd. 2008, 452, 456.
  • 8Sakinttmaa, B.; Lamari-Darkimb, F.; Hirscherc, M. Int. J. Hydrog. Energy 2007, 32, 1121.
  • 9Friedlmeie, R. G.; Arakawa, M.; Hirai, T.; Akiba, E. J. Alloy. Compd. 1999, 292, 101.
  • 10Zhang, Y.; Li, B.; Ren, H.; Guo, S.; Wu, Z.; Wang, X. Int. J. Hydrog. Energy 2009, 34, 2684.

二级参考文献10

  • 1LI Zhinian,LIU Xiaopeng,HUANG Zuo,JIANG Lijun,WANG Shumao.Hydrogen sorption properties of Mg-20wt.%Fe_(23)Y_(8) composite prepared by reactive mechanical alloying[J].Rare Metals,2006,25(z1):247-251. 被引量：1
  • 2LI Zhinian,LIU Xiaopeng,HUANG Zuo,JIANG Lijun,WANG Shumao.Preparation and hydrogen sorption properties of Mg-Cu-Y-H systems[J].Rare Metals,2006,25(z2):89-94. 被引量：1
  • 3Liang G, Boily S, Huot J, Van Neste A, Schulz R. Hydrogen storage in mechanically milled Mg-LaNi5 and MgH2-LaNi5 composites [J]. J. Alloys Compd., 2000, 297: 261.
  • 4Khrussanova M, Bobet J L, Terzieva M, Chevalier B, Radev D, Peshev P. Hydrogen storage characteristics of magnesium mechanically alloyed with YNi5-xMx(X = 0, 1 and 3 intermetallies [J]. J. Alloys Compd., 2000, 307: 283.
  • 5Nore'us D, Olsson L G. The structure and dynamics of hydrogen in Mg2NiH4 studied by elastic and inelastic neutron scattering [J]. J. Chem. Phys., 1983, 78: 2419.
  • 6Zaluska A, Zaluski L. Synergy of hydrogen sorption in ball- milled hydrides of Mg and Mg2Ni [J]. J. Alloys Compd., 1999, 289: 197.
  • 7Orimo S, Fujii H, Tabata M. Synthesis of fine composite particles for hydrogen storage, starting from Mg-YNi2 mixture [J]. J. Alloys Compd., 1994, 210: 37.
  • 8BobetJL, AkibaE, Darriet B. Study of Mg-RE (RE=Co, Ni and Fe) mixture elaborated by reactive mechanical alloying: hydrogen sorption properties [ J ]. Int. J. Hydrogen Energy, 2001, 26: 493.
  • 9Liang G, Huot J, Boily S, Van Neste A, Schulz R. Catalytic effect of transition metals on hydrogen sorption in nanocrysta/lineball milled MgH2-Tm (Tm = Ti, V, Mn, Fe and Ni ) systems [J]. J. Alloys Compd., 1999, 292: 247.
  • 10Songa M Y, Cobet J L, Darriet B. Improvement in hydrogen sorption properties of Mg by reactive mechanical grinding with Cr2O3, Al2O3 and CeO2 [J]. J. Alloys Compd., 2002, 340: 256.

共引文献4

同被引文献58

  • 1周惦武,刘金水,卢远志,张楚慧.镁基储氢材料的吸放氢性能[J].机械工程材料,2008,32(4):5-9. 被引量：9
  • 2Wang, H.; Zhang, J.; Liu, J. W.; Ouyang, L. Z.; Zhu, M. Int. J. Hydrog. Energy 2013, 38 (25), 10932. doi: 10.1016/j. ijhydene.2013.02.075.
  • 3Floriano, R.; Leiva, D. R.; Deledda, S.; Hauback, B. C.; Botta, W. J. Int. J. Hydrog. Energy 2014, 39 (9), 4404.
  • 4Shimada, M.; Higuchi, E.; Inoue, H. J. Alloy. Compd. 2013, 580, S153.
  • 5Kurko, S.; Milanovio, I.; Novakovi6, J. G.; Ivanovi6, N.; Novakovi6, N. Int. J. Hydrog. Energy 2014, 39 (2), 862.
  • 6Song, W. J.; Li, J. S.; Zhang, T. B.; Hou, X. J.; Kou, H. C.; Xue, X.; Hu, R. Trans. Nonferrous Met. Soc. China 2013, 23 (12), 3677. doi: 10.1016/S1003-6326(13)62916-7.
  • 7Mamula, B. E; Novakovi6, J. G.; Radisavljevi6, I.; Ivanovi6, N. Novakovi6, N. Int. J. Hydrog. Energy 2014, 39 (11), 5874. doi: 10.1016/j.ijhydene.2014.01.172.
  • 8Jongh, P. E.; Wagemans, R. W.; Eggenhuisen, T. M.; Dauvillier, B. S.; Radstake, P. B.; Meeldijk, J. D.; Geus, J. W.; Jong, K. P. Chem. Mater. 2007, 19, 6052. doi: 10.1021/cm702205v.
  • 9Kwon, S. N.; Baek, S. H.; Mumm, D. R.; Hong, S. H.; Song, M. Y.; Youp, S. M. lnt. J. Hydrog. Energy 2013, 33 (17), 4586.
  • 10Fan, Y, P.; Peng, X. Y.; Liu, B. Z.; Su, T. C.; Bala, H. d. Rare Earths 2014, 32 (5), 434. doi: 10.1016/S1002-0721(14)60090-9.

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物理化学学报
2011年 第2期

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