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Improvement on the Carnahan-Starling Equation of State for Hard-sphere Fluids

关于硬球流体的Carnahan—Starling状态方程的改进
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摘要 Making use of Weierstrass's theorem and Chebyshev's theorem and referring to the equations of state of the scaled-particle theory and the Pereus-Yevick integration equation, we demonstrate that there exists a sequence of polynomials such that the equation of state is given by the limit of the sequence of polynomials. The polynomials of the best approximation from the third order up to the eighth order are obtained so that the Carnahan-Starling equation can be improved successively. The resulting equations of state are in good agreement with the simulation results on the stable fluid branch and on the metastable fluid branch.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第6期675-679,745,共6页 化学物理学报(英文)
关键词 Hard-sphere fluid Virial coefficient Carnahan-Starling equation of state 硬球流体 维里系数 Carnahan-Starling状态方程
分类号 O [理学]
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