摘要
利用溶胶-凝胶法制备了不同含量的NiO/γ-Al2O3催化剂,通过XRD,XPS和TPR等技术考察了制备方法,NiO含量和焙烧温度对催化剂结构和Ni存在状态的影响,发现溶胶-凝胶法制备的催化剂活性组分NiO与担体γ-Al2O3间具有强相互作用。
A series of NiO/γ-Al_2O_3 catalysts were prepared by sol-gel method. The effects of the methods of preparation, the nickel content and the calcined temperature on the structure and existing forms of nickel species of NiO/γ-Al_2O_3 catalysts were investigated using XRD, XPS and TPR. The results suggested that the interaction between NiO and γ-Al_2O_3 affected the oxidic nickel speies. Nickel oxide was found to appear in the catalysts in three forms, as 'free', 'dispersed' and 'fixed' oxides. The occurrence of the fixed form of the oxide in the catalysts was connected with the formation of nickel aluminate. The effect of the reaction of these different nickel species on the per- formance of the catalysts was dicussed. For the catalysts prepared by sol-gel method, after calcined at higher temperature, nickel species present as a spinel-like structure solid solution, which could re- strain nickel loss and sintering and improve the thermal stability of catalysts.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1999年第8期735-741,共7页
Acta Physico-Chimica Sinica
基金
国家自然科学基金资助!(29392003)
中科院重大基础研究项目
关键词
催化剂
镍基
氧化铝
氧化镍
相互作用
Sol-gel method, NiO/γ-Al_2O_3, Ni species, Interaction between NiO and γ-Al_2O_3