吡啶酰胺基配体与Mn^(2+)、Fe^(3+)、Ru^(3+)配合物的合成和催化环己烯的氧化反应

SYNTHESIS OF COMPLEXES OF LIGANDS CONTAINING PYRIDINECARBOXAMIDE WITH Mn^(2+)、Fe^(3+)、Ru^(3+) AND CATALYTIC OXIDATION OF CYCLOHEXENE

The Complex of the ligands containing pyridinecarboxamide with Mn2+, Fe3=,Ru3+ had been Synthesized. The composition andstructure of the metal complex had been determined by UV, IR.TG, XPS and elemental analysis .When the oxidation of cyclohexenewas catalyzed by the complexes with oxygen as oxided, the conversion reached 45.7%, the seleCtivity of cyclohexenone is 64.6%.Ruthenium complexes exhibits better selectivity for 1,2-cyclohexene oxide.