摘要
Complex Cobalt(III) di[N-(p-methyl)phenyl-2 -pyridinecarboxamide] dihydrate chloride [Co(p-Me-PPA)2(H2O)2] Cl hadbeen synthesised. The single crystal strUcture of the metal complex had been successfully prepared and determined by fourcircle single crystal diffractometer. When the oxidation of cyclohexene was catalyzed by [Co(p-Me-PPA)2(H2O)2]Cl withmolecular oxygen as oxidant, the conversion reached 59% , the selectivity of cyclohexenone being 75%.
Complex Cobalt(III) di[N-(p-methyl)phenyl-2 -pyridinecarboxamide] dihydrate chloride [Co(p-Me-PPA)2(H2O)2] Cl hadbeen synthesised. The single crystal strUcture of the metal complex had been successfully prepared and determined by fourcircle single crystal diffractometer. When the oxidation of cyclohexene was catalyzed by [Co(p-Me-PPA)2(H2O)2]Cl withmolecular oxygen as oxidant, the conversion reached 59% , the selectivity of cyclohexenone being 75%.
出处
《化学研究与应用》
CAS
CSCD
1999年第5期537-538,共2页
Chemical Research and Application
关键词
吡啶甲酰胺
钴配合物
环己烯
氧化
催化剂
pyridinecarboxamide ligand, cobalt complex single crystal, cyclohexene, O2, catalyticoxidation
