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丙烯酰胺在铝表面的电化学聚合涂层 被引量：1

Polyacrylamide Coating on Aluminium Formed by in situ Electrochemical Polymerization
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摘要 Polyacrylamide coating was formed on aluminium cathode by in situ electrochemical polymerization at constant potential. The influences of supporting electrolytes, cell potential and monomer concentration on the performance and morphology of the coating have been studied. Coating with thickness up to 10 μm were obtained by polymerization of acrylamide solution containing 0 05 mol/L AlCl 3 for 1 h at potential of 8.0 V. The morphology and structure of the coating have been examined by FTIR. The mechanism of ECP has been discussed briefly. Polyacrylamide coating was formed on aluminium cathode by in situ electrochemical polymerization at constant potential. The influences of supporting electrolytes, cell potential and monomer concentration on the performance and morphology of the coating have been studied. Coating with thickness up to 10 μm were obtained by polymerization of acrylamide solution containing 0 05 mol/L AlCl 3 for 1 h at potential of 8.0 V. The morphology and structure of the coating have been examined by FTIR. The mechanism of ECP has been discussed briefly.
作者 吴少晖 张曦 陶映初
机构地区 武汉大学环境科学系
出处 《应用化学》 CAS CSCD 北大核心 1999年第4期105-107,共3页 Chinese Journal of Applied Chemistry
关键词 丙烯酰胺 电化学聚合 铝阴极 涂层 聚丙烯酰胺 acrylamide,electrochemical polymerization,aluminium cathode
分类号 O646.54 [理学—物理化学] O633.22 [理学—高分子化学]
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参考文献2

  • 1董绍俊，化学修饰电极，1995年，297页
  • 2陈衍珍，高等学校化学学报，1986年，7卷，917页

同被引文献11

  • 1朱毅■,赵凤云.邻氨基苯酚的电化学聚合[J].高等学校化学学报,1993,14(12):1668-1670. 被引量：6
  • 2Long D D,Marx K A,Zhou T. Amperometric Hydrogen Peroxide Sensor Electrodes Coated with Electropolymerized Tyrosine Derivative and Phenolic Films[J].J Electroanal Chem,2001 ,SOle 1) :107-113.
  • 3Gozen B, Berrin D D. Anticorrosive Properties of Electrosynthesized Poly ( m-aminophenol) on Copper from Aqueous Phenylphosphonic Acid Solution[J]. Prog Org Coat, 2009 ,64 ( 1 ) : 57 -66.
  • 4Noureddine B T , Andre S. Electrochemical Removal of Phenol in Alkaline Solution: Contribution of Anodic Polymerization on Different Electrode Materials[J]. Elechtrochim Acta, 2009 ,54 : 48094816.
  • 5Hideki K, Y ohsuke N , Mikio K, et al. Electrochemical Oxidation of Bisphenol A: Application to the Removal of Bisphenol A Using a Carbon Fiber Electrode[J]. Chemosphere,2001 ,45(1) :3743.
  • 6Hou H Y , Vacandio F, Di Vona M L, et al. Sulfonated Polyphenyl Ether by Electropolymerization[J]. Electrochim Acta, 2012,81 (1) :58-63.
  • 7Hou H Y,Di Vona M L,Knauth P. Durability of Sulfonated Aromatic Polymer for Proton-exchange-membrane Fuel Cells[J]. Chem Sus Chem,2011,4(1l) :1526-1536.
  • 8Joseph 0, Fethi B, Tebello N. Electro-oxidation of Phenol and Its Derivatives on Poly-Ni( OH) TPhPyPc Modified Vitreous Carbon Electrodes[J].J Electroanal Chem,2005 ,576(1) :323-332.
  • 9Di Vona M L, Sgreccia E, Tamilvanan M, et al. High Ionic Exchange Capacity Polyphenylsulfone ( SPPSU) and Polyethersulfone ( SPES) Cross-linked by Annealing Treatment: Thermal Stability, Hydration Level and Mechanical PropertiesJ J].J Membr Sci,2010,354(l) :134-141.
  • 10廖川平.电化学聚合[J].化学通报,2000,63(2):37-41. 被引量：10

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应用化学
1999年 第4期

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