腺嘌呤取代锌卟啉配合物的自组装研究

Studies on Self assembly of Porphyrin Zinc with Adenine

合成了一种新型的带有腺嘌呤取代基的锌卟啉并对其进行了表征． 结果表明， 腺嘌呤取代基与中心金属锌的轴向配位驱动了自组装． 分子量的测量及紫外可见和荧光光谱表明， 存在由自组装而产生的卟啉低聚物．

A new zinc porphyrin with an adenine substituted was synthesized and characterized by 1H NMR and IR spectroscopy and elemental analysis. The coordination of adenine substituted to the central zinc leads to self assembly. The results of vapor pressure osmometry and visible spectroscopy and fluorescence spectrophotometry revealed the presence of a stable self assembled complex.