由特殊相互作用导致的高分子间的络合Ⅸ.聚(苯乙烯-co-4-乙烯基苯酚)/聚(苯乙烯-co-4-乙烯基吡啶)在本体中的相容-络合行为

INTER MACROMOLECULAR COMPLEXATION DUE TO SPECIFIC INTERACTIONSⅨ. MISCIBILITY AND COMPLEX ATION BEHAVIOR OF POLY( STYRENE-co-4- VINYLPHENOL)/ POLY ( STYRENE-co-4- VINYLPYRIDINE) IN BULK

采用结合物理老化技术的示差扫描量热法（ Ｄ Ｓ Ｃ） 以及非辐射能量转移荧光光谱法（ Ｎ Ｒ Ｅ Ｔ） 研究了聚（ 苯乙烯ｃｏ４乙烯基苯酚） （ Ｓ Ｔ Ｖ Ｐｈ） 与聚（ 苯乙烯ｃｏ４乙烯基吡啶）（ Ｓ Ｔ Ｖ Ｐｙ） 共混体系在本体中的相容与络合行为．当 Ｓ Ｔ Ｖ Ｐｈ 中 Ｏ Ｈ 含量为３ ，６ ，９ ｍ ｏｌ ％ 时，可以分别与吡啶基含量是２５ ，５０ ，７５ ｍｏｌ ％ 的 Ｓ Ｔ Ｖ Ｐｙ 实现相容， Ｏ Ｈ 含量更高时还可进一步形成络合，表现为远较 Ｆｏｘ 方程预示值高的 Ｔｇ 和窄的转变温度区间．此外。

The miscibility and complexation behavior of poly(styrene co 4 vinylphenol)( S T V Ph) and poly(styrene co 4 vinylpyridine)( S T V Py) in bulk have been investigated bydifferential scanning calorimetry ( D S C) combined with physical aging as well as non radiative energy transfer ( N R E T) fluorospectroscopy . It has been found that when thehydroxylcontent in S T V Ph reaches 3 ,6 ,9 mol% ,the miscibility of S T V Ph with S T V Pycan be achieved which contains 25 ,50 ,75 mol% vinylpyridine units ( V Py) respectively . Itisnoticeable that when the hydroxyl content is further increased ,complex formation betweenthe components occurs. An apparent casting solvent effect on both miscibility andcomplexation has been also discussed .