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一种二维吡啶-3-乙酸锌配合物的水热合成及其晶体结构 被引量：7

Hydrothermal Synthesis and Crystal Structure Determination of One 2-D Zinc(Ⅱ) Complex with 3-Pyridinecarboxylate ligand
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摘要 该文以氯化锌和吡啶-3-乙酸为原料采用水热法合成一种尚未见报道的配位聚合物,并通过元素分析、红外(IR)、单晶X射线、热重分析(TGA)对其进行了表征.单晶X射线分析结果表明:晶体结构中有一个独立的锌原子,来自两给吡啶环的氮原子[Zn-N=2.172(8)],两个羧基的氧原子[Zn-O=2.089(1)]和两个水的氧原子[Zn-O=2.129(8)]与其配位.该结构通过桥联配体吡啶-3-乙酸的作用得到了一个二维层状结构,且该结构中存在着配位水的氢与羧基氧之间形成的氢键,同时,相邻的层状结构之间通过微弱的C-H…O氢键向三维空间拓展. A coordination polymer containing divalent Zinc and 3-pyridylacetic acid（HL） has been obtained by hydrothermal synthesis and characterized by element alanalysis,IR and X-ray crystallography.The X-ray crystallography indicates that ZnⅡ ion is coordinated by two pyridyl N atoms[Zn-N = 2.172（8） ],two carboxylate O atoms [Zn-O = 2.089（1） ] and two water molecules[Zn-O = 2.129（8） ].This complex,Zn（L）2（H2O）2,displays two-dimensional layers via bridging 3-pyridylcarboxylate ligands in the unit.Adjacent two-dimensional layers are connected by hydrogen bonding between aquo ligands and unligated carboxylate oxygen atoms.Meanwhile,weak interlayer hydrogen bonding（C-H…O） is observed,assembling into the pseudo three-dimensional structure.
作者 庄季昌 罗志荣 武巧兰 张峰 郝虎君 尹显洪
机构地区 广西民族大学化学与生态工程学院 广西大学化学化工学院
出处 《广西民族大学学报（自然科学版）》 CAS 2010年第4期82-85,共4页 Journal of Guangxi Minzu University ：Natural Science Edition
基金 国家自然科学基金(20761002) 广西自然科学基金(0832080) 广西民族大学研究生教育创新计划项目(gxun-chx2010080)
关键词 配位聚合物 吡啶羧酸 晶体结构 锌 coordination polymer pyridylcarboxylate crystal structure zinc
分类号 O614.711 [理学—无机化学]
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参考文献16

  • 1Adams, H. , Clunas, S. , Fenton, D. E. et al. The systematic generation of monodentate bridging ethanoates in dinuclear nickel (II) complexes of asymmetric compartmental ligands [J]. J. Chem, Soc. , Dalton Trans. 2002, 441 - 448.
  • 2Rowsell, J. L. C. , Yaghi, O. M. Strategies for Hydrogen Stor- age in Metal--Organic Frameworks[J]. Angew. Chem. Int. Ed. 2005, 44, 4670-4679.
  • 3Tarulli, S. H. , Quinzani, O. V. , Piro, O. E. , Castellano, E. E. , Baran, E.J. Structural and spectroscopic characterization of bis(thiosaccharinato)bis(benzimidazole)cadmium(II)[J]. J. Mol. Struct., 2006, 797(1 - 3), 56 - 60.
  • 4Muniappan, S., Lipstman, S., George, S., and Goldberg, I. Porphyrin Framework Solids. Synthesis and Structure of Hybrid Coordination Polymers of Tetra(carboxyphenyl)porphyrins and Lanthanide-- Bridging Ions[J]. Inorg. Chem. 2007, 46, 5544- 5554.
  • 5Braverman, M. A. , Nettleman, J. H. , Supkowski, R. M. , and LaDuea, R. L. Copper Phthalate Coordination Polymers Incorpo- rating Kinked Dipyridyl Ligands: An Unprecedented 8--Connected Network and One--Dimensional Chiral Nanobarrels with Hydro- phobic Channels Constructed from Septuple Helical Motifs[J]. In- org. Chem. 2009, 48, 4918-4926.
  • 6Borisova, N. E. , Reshetova, M. D. , and Ustynyuk, Y.A. Metal --free methods in the synthesis of macroeyclie Schiff bases[J]. Chem. Rev. , 2007, 107, 46 - 79.
  • 7Deluzet, A. , Maudez, W. , Daiguebonne, C. , and Guillou, O. Interplane Distances Modulation in Lanthanide--Based Coordina- tion Polymers[J].Crystal Growth & Design, 2003, 3, 475-479.
  • 8Ciurtin, D. M. , Pschirer, N. G. , Smith, M. D. , Bunz, U. H. F. , and Zur Loye, H.C. Two luminescent coordination polymers with a triple-- helix structure: HgX2 (C31H24N2) · CH2Cl2 (X = Cl and Br)[J]. Chem. Mater., 2001, 13, 2743 -2745.
  • 9Sposato, L. K. , Nettleman, J. H. , Braverman, M. A. , Sup- kowski, R. M. , and LaDuca, R. L. Synthesis and Magnetic Prop- erties of Dual- Ligand Divalent Copper Coordination Polymers with Rhomboid Layer, Archimedean Grid, and Sell--Penetrated Network Topologies[J]. Crystal Growth & Design, 2010, 10, 335 -343.
  • 10Zakrzewski, G. , and Saceoni, L. Four--, ? ve and six--coordi- nated nickel(II) and cobalt(II) complexes of Schiff bases derived from pyridine--2--earboxaldehyde and N, N--substituted ethyl- enediamines[J]. Inorg. Chem. , 1968, 7, 1034 -1036.

同被引文献78

  • 1毕思玮,高恩庆,田君濂,李延团,田来进,刘树祥,李桂芝.N－亚水杨基氨基酸3d金属配合物的合成、表征和抑菌活性[J].应用化学,1995,12(6):13-16. 被引量：48
  • 2黄雪峰,钱坤.消旋的有机二磺酸三邻菲咯啉锌配合物(英文)[J].无机化学学报,2005,21(9):1437-1438. 被引量：6
  • 3谢永荣,叶琼.有机二磺酸二邻菲咯啉二水合锌配合物(英文)[J].无机化学学报,2005,21(9):1441-1442. 被引量：9
  • 4K. W. Brammer, P. E. Coates. Pharmaeokinetics of Fluconazole in Pediatric Patient[J]. Eur J. Clin. Microbiol. Infect. Dis. ,1994, 13(4) ,325--329.
  • 5M. Paula Cormick , Marisa Rovera , Edgardo N. Durantini. Syn- thesis, spectroscopic properties and photodynamic activity of a no- vel Zn(II) phthalocyanine substituted by fluconazole group[J]. Journal of Photochemistry and Photobiology A: Chemistry. 2008 (194) ,220--229.
  • 6Lei Zhang , Yun Ling , Feng Peng , Miao Du. Anion--tuned self--assembly of zinc (II) - flueonazole complexes: Crystal struc- tures, luminescent and thermal properties[J]. Journal of Molecu- lar Structure 2007 (829) ,161--167.
  • 7Zhang L, Ling Y, Peng F, et al. Anion tuned self -- assembly of Zn(II) fluconazole complexes : Crystal st ru ctures , luminescent and thermal properties[J]. J Mol Struct , in press.
  • 8Zhao X J, Wan g Q, Du M. Metal directed assembly of 1 - D and 2 --D coordination polymers with f luconazole and dicyanamide co --ligand[J]. Inorg Chim Act a, in press.
  • 9Han H, Song Y, Hou H, et al. A series of metal--organic poly- mers assembled from MCl2( M= Zn, Cd, Co, Cu) : Structures, third--order nonlinear optical and fluorescent propert ies[J]. Dal- ton Trans , 2006,1972.
  • 10J. Wang, S. Hu, M.L. Tong, Eur. J. Inorg[J]. Chem. (2006) 2069.

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广西民族大学学报（自然科学版）
2010年 第4期

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