摘要
详细介绍了甲醇羰基化合成乙酸和乙酸甲酯羰基化合成乙酸酐的过渡金属配合物催化的均相反应体系,包括碘化锂促进的铑配合催化体系,配体促进或稳定的铑配合催化体系,铱配合催化体系,对羰基合成乙酸和乙酸酐的反应过程和反应机理进行了比较。
Homogenous transition metal catalysts for carbonylation of methanol to acetic acid and carbonylation of methyl acetate to acetic anhydride are reviewed.The catalyst system includes lithium iodide promoted Rh-based coordination catalyst,ligand promoted and stabilized Rh-based coordination catalyst and Ir-based coordination catalyst.Further more,the reaction process and mechanism of carbonylation of methanol to acetic acid is compared with that of carbonylation of methyl acetate to acetic anhydride.
出处
《化学世界》
CAS
CSCD
北大核心
2011年第1期57-62,共6页
Chemical World
关键词
羰基化
乙酸
乙酸酐
配合催化
反应机理
carbonylation
acetic acid
acetic anhydride
coordination catalysis
reaction mechanism