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UP/纳米CaCO_3复合材料体积收缩性能的研究 被引量:1

RESEARCH ON VOLUME SHRINKAGE PROPERTY OF UNSATURATED POLYESTER/NANO-CaCO_3
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摘要 研究了纳米CaCO3对不饱和聚酯树脂(UP)体积收缩性能的影响及其作用机理。结果表明,随着纳米CaCO3用量的增加,UP/纳米CaCO3复合材料的体积收缩率先下降后上升;用不同偶联剂对填料进行表面处理后,复合材料的体积收缩率较未用偶联剂处理的复合材料低,且用偶联剂硬脂酸处理填料比用偶联剂KH-570更有利于复合材料体积收缩率的下降。 The effect and mechanism of nano-CaCO3 on the volume shrinkage of the unsaturated polyester(UP) was studied. With the increasing of the fillers in the UP/CaCO3 composites, the volume shrinkage ratio of the composites was decreased first, and then increased. Comparing with the composites obtained with the CaCO3 fillers untreated with coupling agent, the composites obtained with the CaCO3 fillers treated with different coupling agent had smaller volume shrinkage ratio. The volume shrinkage ratio of composites applied with coupling agent stearic acid was lower than that of composites applied with coupling agent KH -570.
出处 《工程塑料应用》 CAS CSCD 北大核心 2011年第1期61-63,共3页 Engineering Plastics Application
基金 河南科技大学人才科研基金项目(05-71) 河南科技大学校科研基金项目(2006ZY029)
关键词 纳米CACO3 不饱和聚酯 体积收缩 偶联剂 nano-CaC03, unsaturated polyester, volume shrinkage, coupling agent
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  • 1庞正智,林晓东.光固化涂层相对内应力与体积收缩率的研究[J].北京化工大学学报(自然科学版),1995,22(4):22-26. 被引量:29
  • 2张力德 牟季美.纳米材料和纳米结构[M].北京:科学出版社,2001.146-147.
  • 3SUH D J, LIM Y T, PARK O. The property and-formation mechanism of unsaturated polyester-layered silicate nanocomposite depending on the fabrication methods [J]. Polymer, 2000, 41 (24) : 8557 - 8563.
  • 4BHARADWAJ R K, MEHRABI A R, HAMILTON C, et al . Structure property relationships in cross-linked polyester-clay nanocomposites [J]. Polymer, 21302, 43 (13) : 3699 - 3705.
  • 5KRISTOFER G E , JACOBSEN T K, PYRZ R. Synthesis of unsaturated polyesters for improved interfacial strength in carbon fibre composites, Composites Part A: Applied Science and Manufacturing, 2002, 33 (9): 1239-1252.
  • 6KORNMANN X , BERGLUND L A , STERTE J. Nanocomposites based on montmorillonite and unsaturated polyester [ J ]. Polym Eng Sci, 1998, 38 (8) : 1351 - 1358.
  • 7BARAN I A , ULKU Y . Mechanical properties of unsaturated polyester/montmorillonite composites [J]. Mater Res Soc Symp - Proc, 2002, 703: 387- 392.
  • 8Liu C J, Kiasat M S, Nijhof A H J, et al. Effect of the addition of a low profile additive on the curing shrinkage of an unsaturated polyester resin [J]. Polymer Engineering and Science, 1999, 39(1): 18-25.
  • 9Li W, Lee J L. Shrinkage control of low-profile unsaturated polyester resins cured at low temperature [J]. Polymer, 1998, 39(23) : 5677-5687.
  • 10Boyard N, Vayer M, Sinturel C, Erre R. Phase- separation mechanism and corresponding final morphologies of thermoset blends based on unsaturated polyester and low-molar-weight saturated polyester[J].Journal of Applied Polymer Science, 2005, 95(6): 1459-1472.

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