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SYNTHESIS OF POLYELECTROLYTIC POLYACETYLENE DERIVATIVES BY QUATERNIZATION OF POLY(PYRIDYLACETYLENE)

SYNTHESIS OF POLYELECTROLYTIC POLYACETYLENE DERIVATIVES BY QUATERNIZATION OF POLY(PYRIDYLACETYLENE)
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摘要 Functional polyacetylenes containing pyridinium side groups(PPyA-MX,X = Br and I) were successfully synthesized.Spectroscopic techniques such as ^1H-NMR,^(13)C-NMR,and FTIR spectroscopy were used to characterize the structure of the obtained polymers.The characterization data were well consistent with the expected macromolecular structures.PPyA-MI had good solubility in polar organic solvents and low solubility in water,while PPyA-MBr had good solubility in both polar organic solvents and water. Functional polyacetylenes containing pyridinium side groups(PPyA-MX,X = Br and I) were successfully synthesized.Spectroscopic techniques such as ^1H-NMR,^(13)C-NMR,and FTIR spectroscopy were used to characterize the structure of the obtained polymers.The characterization data were well consistent with the expected macromolecular structures.PPyA-MI had good solubility in polar organic solvents and low solubility in water,while PPyA-MBr had good solubility in both polar organic solvents and water.
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2011年第2期133-140,共8页 高分子科学(英文版)
基金 supported by the National Natural Science Foundation of China(Nos.20634020,5074046016 and 50703033) the Ministry of Science&Technology(No.2009CB623605) the Research Grants Council of Hon Kong(Nos.603008,602707 and 602706) the support from the Cao Guangbiao Foundation of Zhejian University
关键词 Polyacetylene derivative POLYELECTROLYTE Characterization Water solubility Thermal stability Polyacetylene derivative Polyelectrolyte Characterization Water solubility Thermal stability
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