摘要
作者总结了近年来金属胺基化合物-氢化物体系、氨硼烷及其衍生物储氢材料的研究进展。分别重点介绍了这些材料体系的储氢性能、反应机理及反应热力学和动力学性质,并在此基础上强调了储氢材料的设计理念,即改变材料化学组成调变其热力学性能,催化修饰以提升材料脱氢动力学性能。
Recent progress on hydrogen storage over amide-hydride system, ammonia borane and its derivatives is reviewed. Hydrogen storage performance, mechanism, thermodynamic, and kinetic properties of each storage system are introduced in detail. We emphasize the significances of compositional change and catalyst decoration during the design of next generation hydrogen storage materials, which are essential for the improvement of thermodynamic and kinetic performances, respectively.
出处
《自然杂志》
北大核心
2011年第1期27-30,31-34,共8页
Chinese Journal of Nature
基金
国家高技术研究发展计划(2009AA05Z108)
国家重点基础研究发展计划(2010CB631304)
关键词
储氢材料
反应机理
金属-氮-氢
氨硼烷
hydrogen storage material, reaction mechanism, metal-N-H, ammonia borane
