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微波辅助合成烷基氧糖苷化合物 被引量：1

Microwave-Assisted Synthesis of Alkyl Glucopyranosides
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摘要 在糖类化合物合成中,微波辅助技术是一种有效手段。应用微波辅助技术研究了五乙酰基保护葡萄糖与直链醇在固体酸蒙脱石K-10和4×10-10m的分子筛作用下的烷基氧糖苷化合物的合成,实现了对糖苷化反应产物构型的有效控制,并推测烷基糖苷类衍生物的合成反应机理。 The microwave-assistance was proved as an efficient approach to distinctly shorten the reaction time in glycochemisty.The microwave-assisted synthesis of alkyl glucopyranosides at the peracetylated glucose and straight chain alcohols was studied in the presence of montmorillonite K-10 and（4×10^-10 m） molecular sieves.The configuration of glucopyranoside was successfully controlled. The possible mechanism is also proposed.
作者 薛佳 陈国荣
机构地区 华东理工大学结构可控先进功能材料及其制备教育部重点实验室
出处 《华东理工大学学报（自然科学版）》 CAS CSCD 北大核心 2011年第1期50-54,共5页 Journal of East China University of Science and Technology
基金 国家自然科学基金项目(20876045) 上海市科委项目(10410702700)
关键词 微波 固体酸 直链醇 糖苷化反应 microwave solid acid straight chain alcohols glycoside
分类号 O629.13 [理学—有机化学]
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参考文献23

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二级参考文献4

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共引文献9

同被引文献11

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引证文献1

华东理工大学学报（自然科学版）
2011年 第1期

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