Photocatalytic H_2 evolution activity of CuO/ZrO_2 composite catalyst under simulated sunlight irradiation

Zirconia-supported CuO(CuO/ZrO2) composite photocatalysts were successfully synthesized via citric acid-assisted sol-gel technique.For comparison,CuO/ZrO2 materials were also prepared by solid state reaction and co-precipitation method.The as-prepared powders were characterized by X-ray diffractometry(XRD),transmission electron microscopy(TEM),and thermogravimetric-differential thermal analysis(TG-DTA).The photocatalytic activity of CuO/ZrO2 catalyst was investigated based on the H2 evolution from oxalic acid solution under simulated sunlight irradiation.The effects of molar ratio of CuO to ZrO2,preparation method,phase change with the calcination temperature and the durability on the photocatalytic activity of the photocatalyst were investigated in detail.It is found that the optimal activity of photocatalytic H2 evolution(2.41 mmol·h-1·g-1) can be obtained when CuO/ZrO2 composite photocatalyst is synthesized by sol-gel technique and the mole ratio of CuO to ZrO2 is 40%.The activity of copper oxide supported on monoclinic ZrO2 calcined at higher temperature is much higher than that on tetragonal ZrO2 calcined at lower temperature,and the best calcination temperature is 900 ℃.

Zirconia-supported CuO （CuO/ZrO2） composite photocatalysts were successfully synthesized via citric acid-assisted sol-gel technique. For comparison, CuO/ZrO2 materials were also prepared by solid state reaction and co-precipitation method. The as-prepared powders were characterized by X-ray diffractometry （XRD）, transmission electron microscopy （TEM）, and thermogravimetric-differential thermal analysis （TG-DTA）. The photocatalytic activity of CuO/ZrO2 catalyst was investigated based on the H2 evolution from oxalic acid solution under simulated sunlight irradiation. The effects of molar ratio of CuO to ZrO2, preparation method, phase change with the calcination temperature and the durability on the photocatalytic activity of the photocatalyst were investigated in detail. It is found that the optimal activity of photocatalytic H2 evolution （2.41 mmol.h i.g-~） can be obtained when CuO/ZrO2 composite photocatalyst is synthesized by sol-gel technique and the mole ratio of CuO to ZrO2 is 40%. The activity of copper oxide supported on monoclinic ZrO2 calcined at higher temperature is much higher than that on tetragonal ZrO2 calcined at lower temperature, and the best calcination temperature is 900 ℃.