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苯甲羟肟酸配合物催化降解甲基橙 被引量:5

Synthesis and catalysis study of benzyl hydroxamic acid complexes
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摘要 采用苯甲羟肟酸为配体,与Cu(Ⅱ)、Mn(Ⅱ)、Fe(Ⅲ)氯化物配位制备了系列配合物。通过红外光谱(IR)对合成的化合物进行结构分析,推断了配合物可能的结构,并将其用作催化剂,催化H_2O_2氧化降解甲基橙,考察这些金属配合物的催化氧化性能和影响条件。 Cu(Ⅱ)、Mn(Ⅱ)、Fe(Ⅲ) complexes were prepared using benzyl hydroxamic acid as ligand.These complexes were characterized by IR,and the possible structures were discussed. These complexes were used as catalyst in the oxidation degeneration reactions of H_2O_2 and methyl orange,and the reaction conditions were studied.
作者 邓强 徐敬芳
出处 《石油化工应用》 CAS 2011年第1期5-7,共3页 Petrochemical Industry Application
关键词 羟肟酸 过渡金属配合物 氧化降解 hydroxamic acid complexes oxidation degeneration
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