摘要
以3-羧基水杨醛和乙二胺为原料,采用微波辐射辅助液相合成法合成了N-3-羧基水杨醛缩乙二胺配体;然后将该配体与四水醋酸镍络合,合成了一种新型的Schiff碱单核镍配合物。通过元素分析、红外光谱、质谱对Schiff碱配体及其镍配合物进行了表征。
Under microwave irradiation,a novel mononuclear nickel complex of Schiff base was synthesized by liquid phase reaction of Ni(Ac)2·4H2O with ligand N-3-carboxylsalicylidene-ethylenediimine,which was obtained from the reaction of 3-carboxylsalicylidene with ethylenediimine.The ligand and the complex were characterized by elemental analysis,IR and MS.
出处
《化学与生物工程》
CAS
2011年第2期12-13,共2页
Chemistry & Bioengineering
基金
国家自然科学基金青年基金资助项目(51003051)
青岛农业大学博士启动基金资助项目(630924)