N-3-羧基水杨醛缩乙二胺Schiff碱单核镍配合物的微波辅助合成

Microwave Assisted Synthesis of Mononuclear Nickel Complex of Schiff Base N-3-Carboxylsalicylidene-ethylenediimine

以3-羧基水杨醛和乙二胺为原料,采用微波辐射辅助液相合成法合成了N-3-羧基水杨醛缩乙二胺配体;然后将该配体与四水醋酸镍络合,合成了一种新型的Schiff碱单核镍配合物。通过元素分析、红外光谱、质谱对Schiff碱配体及其镍配合物进行了表征。

Under microwave irradiation,a novel mononuclear nickel complex of Schiff base was synthesized by liquid phase reaction of Ni（Ac）2·4H2O with ligand N-3-carboxylsalicylidene-ethylenediimine,which was obtained from the reaction of 3-carboxylsalicylidene with ethylenediimine.The ligand and the complex were characterized by elemental analysis,IR and MS.