摘要
A metal-organic coordination polymer formulated as [Ni（cbba） 2 （bipy）（H 2 O） 2 ] n 1 （H 2 cbba=2-（4-chlorine-benzoyl）benzoic acid,bipy=4,4-bipyridine） has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.The title compound crystallizes in the triclinic system,space group P1 with a=5.4550（4）,b=11.4099（8）,c=15.3135（11）,α=68.7680（10）,β=81.3470（10）,γ=79.3450（10）o,V=869.48（11） 3,C 38 H 28 Cl 2 N 2 NiO 8,M r=770.23,D c=1.471 g/cm 3,μ（MoKα）=0.768 mm 1,F（000）=396,Z=1,the final R=0.0456 and wR=0.1171 for 2477 observed reflections （I 2σ（Ⅰ））.It exhibits a one-dimensional chain-like structure.
A metal-organic coordination polymer formulated as [Ni（cbba） 2 （bipy）（H 2 O） 2 ] n 1 （H 2 cbba=2-（4-chlorine-benzoyl）benzoic acid,bipy=4,4-bipyridine） has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.The title compound crystallizes in the triclinic system,space group P1 with a=5.4550（4）,b=11.4099（8）,c=15.3135（11）,α=68.7680（10）,β=81.3470（10）,γ=79.3450（10）o,V=869.48（11） 3,C 38 H 28 Cl 2 N 2 NiO 8,M r=770.23,D c=1.471 g/cm 3,μ（MoKα）=0.768 mm 1,F（000）=396,Z=1,the final R=0.0456 and wR=0.1171 for 2477 observed reflections （I 2σ（Ⅰ））.It exhibits a one-dimensional chain-like structure.
基金
the Science and Technology Research Projects of the Education Department of Jilin Province (No. 2009. 272)
