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Synthesis of Spiro Dihydrofurans and 1,8-Dioxo-xanthenes via DABCO Catalyzed Tandem Reaction of Aldehyde with Cyclohexane-1,3-dione and Dimedone

Synthesis of Spiro Dihydrofurans and 1,8-Dioxo-xanthenes via DABCO Catalyzed Tandem Reaction of Aldehyde with Cyclohexane-1,3-dione and Dimedone
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摘要 The 1,4-diazabicyclo[2.2.2]octane(DABCO) catalyzed reaction of cyclohexane-1,3-dione or dimedone with various aldehydes in acetonitrile resulted in the polysubstituted tetraketones, spiro dihydrofurans or 1,8-dioxo-xanthenes derivatives as main products respectively according to the structure of reactants and reaction conditions. The 1,4-diazabicyclo[2.2.2]octane(DABCO) catalyzed reaction of cyclohexane-1,3-dione or dimedone with various aldehydes in acetonitrile resulted in the polysubstituted tetraketones, spiro dihydrofurans or 1,8-dioxo-xanthenes derivatives as main products respectively according to the structure of reactants and reaction conditions.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2011年第1期49-53,共5页 高等学校化学研究(英文版)
基金 Supported by the National Natural Science Foundation of China(No20972132)
关键词 Tandem reaction DIMEDONE Spiro dihydrofuran Tetraketone 1 8-Dioxo-xanthene Tandem reaction Dimedone Spiro dihydrofuran Tetraketone 1,8-Dioxo-xanthene
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