摘要
反应堆的一种新类型,与侵犯旋转溪流的包装的床(IS-RPB ) 和卷管子展示了,被设计并且过去常从重氮基盐由水解作用准备 p-hydroxybenzaldehyde (哲学学士) 。操作参数的影响例如反应温度,反应时间和高严肃因素,在哲学学士的收益上被调查。与传统的水壶类型反应堆相比,有新反应堆的哲学学士的收益显著地被增加,反应时间短得多。在最佳条件下面,哲学学士的收益从 51% ~ 84.1% 被增加。反应堆为用一个连续过程代替传统的批模式操作提供一个机会。
A new type of reactor,featured with impinging stream-rotating packed bed(IS-RPB)and coil pipes,was designed and used to prepare p-hydroxybenzaldehyde(PHB)by hydrolysis from diazonium salts.The influence of operating parameters,such as reaction temperature,reaction time and high gravity factor,on the yield of PHB was investigated.Compared with the traditional kettle-type reactor,the yield of PHB with the new reactor is increased significantly and the reaction time is much shorter.Under the optimum conditions,the yield of PHB is increased from 51%to 84.1%.The reactor offers an opportunity for replacing the traditional batch mode operation with a continuous process.
基金
Supported by the Science and Technology Key Projects of Shanxi Province(20090321113)